Lithium secondary battery anode member and method for manufacturing the same
AssigneeSumitomo Electric Industries, Ltd.
InventorNobuhiro Ota
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Abstract
A lithium secondary battery anode member of the present invention includes a solid electrolyte film formed on a lithium metal film and is capable of suppressing reduction of the solid electrolyte film over a long period of time. In the lithium secondary battery anode member, the lithium metal film and the solid electrolyte film are laminated on a substrate, the solid electrolyte film contains the composition xLi.yP.zS.wO wherein x, y, z, and w satisfy the relations, 0.2≦x≦0.45, 0.1≦y≦0.2, 0.35≦z≦0.6, and 0.03≦w≦0.13, respectively, (x+y+z+w=1), and the main peaks of an X-ray diffraction pattern of the solid electrolyte film measured by a film method using Cu Kα radiation are at 2θ of about 11° and 30° and each have a half width of 10° or less.
Claims2
A method for producing a lithium secondary battery anode member including a laminate of a lithium metal film and a solid electrolyte film on a substrate, wherein the solid electrolyte film has a crystallinity between amorphous and crystalline states and an X-ray diffraction pattern of the solid electrolyte film has peaks at 2θ of about 11° and 30° with a half width of 10° or less, the method comprising steps of:
- depositing the lithium metal film on the substrate;
- depositing the solid electrolyte film on the lithium metal film by using a mixture of powders of lithium sulfide (Li2S), phosphorus pentasulfide (P2S5) and phosphorus pentoxide (P2O5);
- and
- heating the solid electrolyte film at 75° C. to 170° C. for 5 minutes to 50 hours in a dry inert atmosphere,
- wherein the composition of the solid electrolyte film is xLi.yP.zS.wO wherein x, y, z, and w satisfy the relations, 0.2≦x≦0.45, 0.1≦y≦0.2, 0.35≦z≦0.6, and 0.03≦w≦0.13, respectively, (x+y+z+w=1).
Dependencies are inferred from the claim text.