Bituminous mixtures with a high polymer content
AssigneeENI S.p.A.
InventorsPaolo Italia, Luigi D'Elia
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AssigneeENI S.p.A.
InventorsPaolo Italia, Luigi D'Elia
Estimating the term…
The invention relates to a process for the preparation of mixtures containing bitumen and thermoplastic polymer at a high concentration, stable during storage, with particular characteristics of easy processability and movability which, once diluted, allow modified bitumens to be obtained with high performance characteristics. In particular, the process allows mixtures containing bitumen, thermoplastic polymer and wax, to be prepared, wherein the polymer is in a quantity varying from 5 to 30% by weight with respect to the weight of the mixture consisting of bitumen and polymer, and the wax is in a quantity varying from 4.7 to 16.7% by weight with respect to the weight of the total mixture, and comprises reacting a concentrated mixture (A), stable during storage, containing bitumen and from 5 to 30% by weight of thermoplastic polymer, with a hydrocarbon wax containing at least 40 carbon atoms and having a melting point of at least 700 C., in a weight ratio between the mixture (A) and wax ranging from 100:5 to 100:20, at a temperature ranging from 160 to 2000 C. and for a time ranging from 15 minutes to 7 hours, preferably from 15 to 120 minutes. An object of the invention also relates to new mixtures containing bitumen and thermoplastic polymer at a high concentration and mixtures obtainable from these by dilution.
Method for preparing mixtures consisting of bitumen, thermoplastic polymer and wax, wherein the polymer is in amounts in the range from 5 to 30% by weight with respect to the weight of the mixture made up of bitumen and polymer, and the wax is in amounts in the range from 4.7 to 16.7% by weight with respect to the weight of the total mixture, which consists of reacting a concentrated mixture (A), stable at storage, containing bitumen and thermoplastic polymer in the range of from 5 to 30% by weight, with a hydrocarbon wax containing a number of carbon atoms in the range from 40 to 100 and having a melting temperature in the range from 70° C. to 120° C., in weight ratio between mixture (A) and wax in the range from 100:5 to 100:20, at a temperature in the range from 160 to 200° C. and for a time ranging from 15 minutes to 7 hours, wherein said mixture A is obtained by reacting a bituminous product having;
Concentrated bituminous mixture, stable at storage, consisting of bitumen, thermoplastic polymer and wax, wherein the polymer is in amounts in the range from 5 to 30% by weight with respect to the weight of the mixture made up of bitumen and polymer, and the wax is a hydrocarbon wax containing a number of carbon atoms in the range from 40 to 100 and having a melting point ranging from 70° C. to 120° C., in amounts in the range from 4.7 to 16.7% by weight with respect to the weight of the total mixture, wherein the bitumen has a total asphaltenes, resins, saturates and aromatics content such to meet the requirement that the Ic index be in the range from 0.200 to 0.270 in the expression:
Bituminous mixture, stable at storage, consisting of bitumen, thermoplastic polymer and wax, wherein the polymer is in amounts in the range from 1 to 10% by weight with respect to the weight of the total mixture and the wax is a hydrocarbon wax a number of carbon atoms from 40 to 100 and having a melting point from 70° C. to 120° C., in amounts in the range from 0.5 to 5.0% by weight with respect to the weight of the total mixture, and wherein the thermoplastic polymer is a radial copolymer consisting of blocks of polystyrene and of polybutadiene (SBS) with a styrene/butadiene ratio ranging from 25/75 to 35/65 to and a molecular weight ranging from 100,000 to 400,000.
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