Maleimide-functional monomers in amorphous form
AssigneeDesigner Molecules, Inc.
InventorStephen M Dershem
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Abstract
The present invention provides amorphous maleimide-bismaleimide hybrid mixtures and methods for synthesizing such mixtures by condensation of diamine compounds with maleic anhydride along with one or more additional anhydrides. The invention provides a route to get passed the high melting point and the solubility issues of bismaleimide resins, yet to still obtain the good thermo-mechanical properties of these valuable molecules.
Claims17
A compound mixture, comprising at least one compound of type A, at least one compound of type B and at least one compound of type C
- wherein R1 is selected from the group consisting of an unsubstituted aromatic, a substituted aromatic, an unsubstituted aliphatic, a substituted aliphatic, an unsubstituted cycloaliphatic and a substituted cycloaliphatic moiety, R1 comprising between 2 and about 500 carbon atoms;
- and
- R2 is selected from the group consisting of an unsubstituted alkylene, a substituted alkylene, an unsubstituted cycloakylene and a substituted cycloakylene moiety, R2 comprising between 3 and about 36 carbon atoms, wherein the unsubstituted cycloakylene or a substituted cycloalkylene moiety taken together with the maleimide structure to which it is attached optionally forms a condensed ring structure,
- wherein in the compound mixture the total contents of compound C is between about 3 mol % and about 10 mol % of the mixture.
A compound mixture, selected from the group consisting of mixtures 1-17, wherein mixture 1 comprises compounds 1a and 1b, mixture 2 comprises compounds 2a and 2b, mixture 3 comprises compounds 3a, 3b and 3c, mixture 4 comprises compounds 4a and 4b, mixture 5 comprises compounds 5a and 5b, mixture 6 comprises compounds 6a and 6b, mixture 7 comprises compounds 7a and 7b, mixture 8 comprises compounds 8a and 8b, mixture 9 comprises compounds 9a and 9b, mixture 10 comprises compounds 10a and 10b, mixture 11 comprises compounds 11a and 11b, mixture 12 comprises compounds 12a and 12b, mixture 13 comprises compounds 13a and 13b, mixture 14 comprises compounds 14a and 14b, mixture 15 comprises compounds 15a and 15b, mixture 16 comprises compounds 16a and 16b and mixture 17 comprises compounds 17a and 17, wherein in mixture 3 the total contents of compound 3c is between about 3 mol % and about 10 mol % of the mixture:
An adhesive composition comprising:
- (a) a compound mixture comprising at least one compound of type A, at least one compound of type B and at least one compound of type C
- wherein R1 is selected from the group consisting of an unsubstituted aromatic, a substituted aromatic, an unsubstituted aliphatic, a substituted aliphatic, an unsubstituted cycloaliphatic and a substituted cycloaliphatic moiety, R1 comprising between 2 and about 500 carbon atoms;
- and
- R2 is selected from the group consisting of an unsubstituted alkylene, a substituted alkylene, an unsubstituted cycloakylene and a substituted cycloakylene moiety, R2 comprising between 3 and about 36 carbon atoms, wherein the unsubstituted cycloakylene or a substituted cycloalkylene moiety taken together with the maleimide structure to which it is attached optionally forms a condensed ring structure;
- (b) at least one co-monomer selected from the group consisting of acrylates, methacrylates, maleimides, vinyl ethers, vinyl esters, acrylamides, methacrylamides, maleates, itaconates, fumarates, styrenic compounds, allylic functionalized compounds, epoxies, phenolics and phenyl esters;
- (c) at least one curing initiator;
- (d) a coupling agent;
- and
- (e) a filler.
Dependencies are inferred from the claim text.