Lubricating oil compositions for biodiesel fueled engines
AssigneeExxonMobil Research and Engineering Company
InventorsJacob J. Habeeb, Ramesh Varadaraj, Steven M. Jetter
Life of this patent
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Abstract
Lubricating oil used for the lubrication of engines run on biodiesel fuels are improved in their resistance to oxidation by the addition to said to lubricating oil of particular detergents, and premixed mixtures of particular detergents and anti-oxidants.
Claims11
A method for improving the resistance to oxidation of lubricating oils used to lubricate engines run on biodiesel fuels comprising adding to the lubricating oil an additive amount of a combination of one or more detergents selected from alkaline earth metal salicylate, and hydrocarbyl salicylate, and two anti-oxidants, wherein the two antioxidants are a 50:50 mixture of a hindered phenolic anti-oxidant and a hindered aminic anti-oxidant wherein the weight ratio (active ingredient) of detergent to anti-oxidant is about 1.5 to 1, wherein the one or more detergents and the two anti-oxidants are premixed prior to being added to the lubricating oil and wherein the premix is formed by weighing and adding sequentially to a stirred heat vessel at about 60 deg. C. the one or more detergents and the two anti-oxidants, and mixing in said stirred heat vessel for a time of about 90 minutes, wherein the lubricating oil is a methyl ester and wherein the premix of detergent and anti-oxidant is added to the lubricating oil in a combined amount of about 0.5 wt % (active ingredient).
An additive premixture comprising a combination of one or more detergents selected from alkaline earth metal salicylate, and hydrocarbyl salicylate, and two anti-oxidants, wherein the two antioxidants are a 50:50 mixture of a hindered phenolic anti-oxidant and a hindered aminic anti-oxidant wherein the weight ratio (active ingredient) of detergent to anti-oxidant is about 1.5:1,
- wherein the additive premixture is prepared by premixing the one or more detergents and the two anti-oxidants by weighing and adding sequentially to a stirred heat vessel at about 60 deg. C. the one or more detergents and the two anti-oxidants, and mixing in said stirred heat vessel for a time of about 90 minutes to yield an anti-oxidant/detergent complex, and
- wherein the additive premixture at about 0.5 wt % yields an improved oxidative resistance in methyl ester based lubricating oils used to lubricate engines run on biodiesel fuels in comparison to lubricating oils using the same combination of one or more detergents and two antioxidants that are not premixed.
Dependencies are inferred from the claim text.