US 8,679,228 B2Granted

Method of reusing hydrogen

AssigneeTokuyama Corporation

InventorsAyao Akiyoshi, Tadashi Aimoto

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Abstract

The invention recovers highly pure hydrogen from the exhaust purge gas and reuses it as a hydrogen source in other production steps contributing to greatly reducing the disposal cost and the cost of producing polysilicon. The hydrogen chloride contained in the exhaust gas discharged from the step of depositing polysilicon by using trichlorosilane, is adsorbed by active carbon. The active carbon layer is then purged with the hydrogen gas, and the adsorbed hydrogen chloride is desorbed. Next, the exhaust purge gas is brought into contact with a hydrogen chloride-absorbing solution such as an aqueous solution of sodium hydroxide to remove the hydrogen chloride from the exhaust purge gas and to separate and recover the highly pure hydrogen gas. The recovered hydrogen gas is compressed and is fed as a hydrogen source to other steps of producing, for example, fumed silica.

Claims4

Dependent claims

A method of reusing hydrogen in an exhaust purge gas, comprising:

(1) a hydrogen chloride adsorption step of adsorbing the hydrogen chloride by passing, through an active carbon layer, the exhaust gas discharged from a step of producing polysilicon by reacting hydrogen with a trichlorosilane;
(2) a hydrogen chloride desorption step of desorbing the adsorbed hydrogen chloride by passing a hydrogen gas as the purge gas through the active carbon layer that has adsorbed and held the hydrogen chloride;
(3) a hydrogen recovery step of obtaining the hydrogen gas from which the hydrogen chloride has been removed by bringing, into contact with a hydrogen chloride-absorbing solution, the exhaust purge gas that contains hydrogen and the hydrogen chloride desorbed in said hydrogen chloride desorption step;
and
(4) a hydrogen feed step of compressing the hydrogen gas recovered in said hydrogen recovery step and feeding the hydrogen gas as a hydrogen source for other steps,
wherein said method further comprises
a water washing step of washing with water the hydrogen gas recovered in the hydrogen recovery step prior to the hydrogen feed step, and
a step of bringing the hydrogen gas washed with water in the water washing step into contact with a silane-trapping agent prior to the hydrogen feed step or during the compression in the hydrogen feed step and, thereafter, separating, from the hydrogen gas, the silane-trapping agent that accompanies the hydrogen gas.

5 more elements

Dependencies are inferred from the claim text.

Facts

Application: 13/390,018Filed 13 Sep 2010
Priority: JP 2009-22662930 Sep 2009
Published: US 2012/0137881 A17 Jun 2012
Granted: 25 Mar 2014
Term ends: Not estimatedThe source records don’t support an estimate.

Classification13 codes

C01B 3/52
Separation of hydrogen or hydrogen-containing gases from gaseous mixtures, e.g. purification: by contacting with liquids; Regeneration of used liquids
B01D 53/685
Halogens or halogen compounds: by treating the gases with solids
C01B 3/56
Separation of hydrogen or hydrogen-containing gases from gaseous mixtures, e.g. purification: by contacting with solids; Regeneration of used solids
C01B 7/0725
By adsorption: by active carbon