Tetrazine monomers and copolymers for use in organic electronic devices
AssigneeNational Research Council of Canada
InventorsJianfu Ding, Zhao Li, Naiheng Song
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Abstract
Copolymers of formula (I): where each A is S, Se or C═C; each x is an integer from 1 to 4; each R1 is independently H, F, CN or a C1-C20 linear or branched aliphatic group; Ar is one or more substituted or unsubstituted aromatic units; and, n is an integer 5 or greater, can be formed into films or membranes that are useful as active layers in organic electronic device, such as PV solar cells, providing high power conversion efficiencies and good thermal stability. Such copolymers may be synthesized from monomers of formula (II): by Stille or Suzuki coupling reactions. Such monomers may be synthesized by a variation of the Pinner synthesis.
Claims20
A copolymer of formula (I):
- where each A is S, Se or C═C;
- each x is an integer from 1 to 4;
- each R1 is independently H, F, CN or a C1-C20 linear or branched aliphatic group;
- Ar is one or more substituted or unsubstituted aromatic units;
- and, n is an integer 5 or greater.
Dependencies are inferred from the claim text.