Process, method, and system for removing heavy metals from fluids
AssigneeChevron U.S.A. Inc.
InventorDarrell Lynn Gallup
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Abstract
Trace element levels of heavy metals such as mercury in crude oil are reduced by contacting the crude oil with an iodine source, generating a water soluble heavy metal complex for subsequent removal from the crude oil. In one embodiment, the iodine source is generated in-situ in an oxidation-reduction reaction, by adding the crude oil to an iodine species having a charge and a reductant or an oxidant depending on the charge of the iodine species. In one embodiment with an iodine species having a positive charge and a reducing reagent, a complexing agent is also added to the crude oil to extract the heavy metal complex into the water phase to form water soluble heavy metal complexes which can be separated from the crude oil, for a treated crude oil having reduced levels of heavy metals.
Claims18
A method for treating a crude oil to reduce its mercury level, comprising:
- providing a crude oil containing an oil-water emulsion;
- converting at least a portion of mercury in the crude oil to water soluble mercuric iodide in the oil-water emulsion upon contact with a molecular iodine;
- and
- separating the oil-water emulsion to obtain a water phase containing the water soluble mercuric iodide and a treated crude oil having a reduced concentration of mercury, wherein the treated crude oil contains less than 10 ppb mercury.
A method for treating a crude oil to reduce its mercury level, comprising:
- providing a crude oil containing a water phase;
- converting at least a portion of mercury in the crude oil to water soluble mercuric iodide in the water phase upon contact with molecular iodine in a solvent;
- and
- separating the water phase containing the water soluble mercuric iodide from the crude oil in a phase separation device for a treated crude oil having less than 10 ppb mercury.
Dependencies are inferred from the claim text.