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US 8,618,199 B2Granted
Functionalized high cis-1,4-polybutadiene prepared using novel functionalizing agents
OwnerYoichi F. Ozawa, H. Jerrold Miller +6inventors
InventorsYoichi F. Ozawa, H. Jerrold Miller, Koji Masaki, Koichi Morita, Tatsuo Fujimaki, Tetsuya Omura, Takuo Sone, Iwakazu Hattori
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Abstract
A method for preparing a functionalized polymer comprising the steps of preparing a polymer by polymerizing conjugated diene monomer with a lanthanide-based catalyst, wherein the lanthanide-based catalyst comprises (a) a lanthanide compound, (b) an alkylating agent, and (c) a source of halogen, and reacting the pseudo-living polymer with at least one amide-containing functionalizing agent.
Claims11
A method for preparing a functionalized polymer comprising the steps of:
- preparing a pseudo-living polymer by polymerizing conjugated diene monomer with a lanthanide-based catalyst, wherein the lanthanide-based catalyst comprises (a) a lanthanide compound, (b) an alkyl aluminoxane, and (c) a source of halogen;
- and
- reacting the pseudo-living polymer with at least one functionalizing agent selected from the group consisting of:
- where R1 is a divalent bond or divalent organic group comprising from 0 to about 20 carbon atoms, R2 is a divalent organic group or trivalent organic group in the case where R2 combines with R4 to form a cyclic group, and R4 is a hydrogen atom, a monovalent organic group, or, in the case where R4 combines with R2, R4, may be a divalent organic group, and where Z is a substituent that will react or interact with organic or inorganic filler.
1 more element
Dependencies are inferred from the claim text.