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US 8,617,788 B2Granted
Actinic ray-sensitive or radiation-sensitive resin composition and pattern forming method using the same
AssigneeFUJIFILM Corporation
InventorsTakayuki Kato, Hiroshi Saegusa, Kaoru Iwato, Shuji Hirano, Yusuke Iizuka, Shuhei Yamaguchi, Akinori Shibuya
Life of this patent
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Abstract
An actinic ray-sensitive or radiation-sensitive resin composition, wherein when a film having a film thickness of 100 nm is formed from the actinic ray-sensitive or radiation-sensitive resin composition, the film has a transmittance of 55 to 80% for light at a wavelength of 193 nm, and a pattern forming method using the composition are provided.
Claims13
An actinic ray-sensitive or radiation-sensitive resin composition, comprising
- (A) a resin capable of increasing a solubility of the resin (A) in an alkali developer by an action of an acid;
- (B) a compound capable of generating an acid upon irradiation with an actinic ray or radiation;
- and
- (C) a resin containing at least either a fluorine atom or a silicon atom and a polarity converting group,
- wherein when a film having a film thickness of 100 nm is formed from the actinic ray-sensitive or radiation-sensitive resin composition, the film has a transmittance of 55 to 80% for light at a wavelength of 193 nm,
- wherein an ester group directly bonded to the main chain of a repeating unit is not included in the polarity converting group,
- wherein the resin (C) contains (c′) a repeating unit containing at least either a fluorine atom or a silicon atom and a polarity converting group on one side chain, and
- wherein the component (B) is a compound represented by the following formula (1-1) or (1-2):
- wherein in formula (1-1),
- R13 represents a hydrogen atom, a fluorine atom, a hydroxyl group, an alkyl group, a cycloalkyl group, an alkoxy group, an alkoxycarbonyl group, or a group having a monocyclic or polycyclic cycloalkyl skeleton;
- R14 represents an alkyl group, a cycloalkyl group, an alkoxy group, an alkylsulfonyl group, a cycloalkylsulfonyl group, an alkylcarbonyl group, an alkoxycarbonyl group, or an alkoxy group having a monocyclic or polycyclic cycloalkyl skeleton, and when a plurality of R14's are present, the plurality of R14's are the same or different;
- each R15 independently represents an alkyl group, a cycloalkyl group or a naphthyl group, and two R15's may combine with each other to form a ring;
- l represents an integer of 0 to 2;
- r represents an integer of 0 to 8;
- and
- X− represents a non-nucleophilic anion;
- and in formula (1-2),
- M represents an alkyl group, a cycloalkyl group, an aryl group or a benzyl group and when M has a ring structure, the ring structure may contain an oxygen atom, a sulfur atom, an ester bond, an amide bond or a carbon-carbon double bond;
- each of R1c and R2c independently represents a hydrogen atom, an alkyl group, a cycloalkyl group, a halogen atom, a cyano group or an aryl group, and R1c and R2c may combine with each other to form a ring;
- each of Rx and Ry independently represents an alkyl group, a cycloalkyl group, a 2-oxoalkyl group, an alkoxycarbonylalkyl group, an allyl group or a vinyl group;
- Rx and Ry may combine with each other to form a ring, at least two members of M, R1c and R2c may combine with each other to form a ring, and the ring structure may contain a carbon-carbon double bond;
- and
- X− represents a non-nucleophilic anion.
20 more elements
An actinic ray-sensitive or radiation-sensitive resin composition, comprising:
- (A) a resin capable of increasing a solubility of the resin (A) in an alkali developer by an action of an acid;
- (B) a compound capable of generating an acid upon irradiation with an actinic ray or radiation;
- and
- (C) a resin containing at least either a fluorine atom or a silicon atom and a polarity converting group,
- wherein when a film having a film thickness of 100 nm is formed from the actinic ray-sensitive or radiation-sensitive resin composition, the film has a transmittance of 55 to 80% for light at a wavelength of 193 nm, and
- wherein the resin (A) contains a lactone structure-containing repeating unit represented by the formula (3):
- wherein R7 represents a hydrogen atom, a halogen atom or an alkyl group;
- R8 represents a monovalent organic group having a lactone structure;
- A represents an ester bond or an amide bond;
- R0 represents a methylene group;
- Z represents an ester bond, and
- n represents 1.
9 more elements
Dependencies are inferred from the claim text.