Shaped cellulose manufacturing process combined with a pulp mill recovery system
AssigneeKiram AB
InventorLars Stigsson
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Abstract
Provided is a process for manufacturing shaped cellulose materials from lignocellulose where a dissolving grade pulp is manufactured and dissolved in an aqueous alkaline or acidic solvent system forming a solution suitable for shaping new cellulose structures including fibers, films and cellulose derivatives. At least a part of the spent cellulose dissolving or cellulose shaping chemicals are recovered in one or more unit operations in a pulp mill chemical recovery cycle.
Claims32
A process for manufacturing shaped cellulose material from lignocellulose comprising the steps of:
- a) providing a feed of comminuted lignocellulosic material comprising cellulose, hemicelluloses and lignin;
- b) separating lignin from lignocellulosic feed material by cooking the material at a temperature from between about 110 to 200° C. for a time period of from about 1 hour to 6 hours in an aqueous solution comprising soluble alkali, alkali earth metal or phosphorous compounds, thereby forming a first stream of solid material enriched in cellulose and a second spent liquor stream rich in dissolved lignin;
- c) treating the first stream enriched in cellulose from step b) by at least one of oxygen delignification, bleaching, and alkali extraction, to form a cellulose pulp with a lignin content below about 2 wt %;
- d) treating the second spent liquor stream from step b) comprising dissolved lignin, alkali, alkali earth, phosphorous or sulfur compounds, in a separate chemical recovery system comprising one or more chemical recovery units selected from the group consisting of a spent liquor concentration unit, a gas generator unit, a recovery boiler unit, and a causticising unit, wherein one or more of fresh alkali, alkali earth metal, phosphorous and sulfur compounds are recovered and reformed;
- e) dissolving the cellulose pulp having a lignin content below about 2 wt % from step c) in a solution comprising one or more of alkali, alkali earth, phosphorous, sulfur and molten salt compounds, the solution optionally comprising one or more additives, thereby forming a substantially homogeneous solution comprising dissolved cellulose, thereafter shaping or coagulating the dissolved cellulose into fibers, films or cellulose derivatives, and optionally washing the shaped or coagulated cellulose;
- f) discharging spent chemicals from at least one of:
- f1) the cellulose dissolving step in e),
- f2) the cellulose shaping or cellulose coagulation step in e), and
- f3) the shaped or coagulated cellulose washing step in e);
- g) recycling the spent chemicals in one or more units of the chemical recovery system of step d);
- wherein the spent chemicals are recovered and reformed;
- h) using fresh cellulose dissolving and/or cellulose shaping chemicals recovered from the chemical recovery system in step g) in the respective cellulose dissolving and/or cellulose shaping steps in e).
A process for manufacturing shaped cellulose material from cellulose pulp and the recovery and recycling of spent cellulose dissolving and cellulose shaping chemicals, comprising the steps of:
- a) providing a feed of cellulose pulp having a lignin content below about 2 wt %;
- b) dissolving the cellulose pulp from a) in a solution comprising one or more of alkali metal, alkali earth metal, phosphorous, sulfur and molten salt compounds, the solution optionally comprising one or more additives, thereby forming a substantially homogeneous solution comprising dissolved cellulose;
- wherein spent cellulose dissolving chemicals are optionally discharged;
- c) shaping the dissolved cellulose from step b) into fibers, films or cellulose derivatives;
- wherein spent cellulose shaping chemicals are discharged;
- and
- d) recycling the spent chemicals discharged in step c) and optionally also in step b) in a separate chemical recovery system comprising one or more chemical recovery units selected from the group consisting of a liquor concentration unit, a recovery boiler unit, a gas generator unit, and a causticising unit, wherein the chemical recovery units are integrated in a kraft, sulfite, or soda pulp mill.
Dependencies are inferred from the claim text.