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US 8,616,283 B2Granted
Process for treating water in heavy oil production using coated heat exchange units
AssigneeE. I. Du Pont de Nemours and Company
InventorsLaurence Waino McKeen, Michael Albert Hooper
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Abstract
A process for treating a water stream produced in the recovery of heavy oil from geological formations. The process includes use of a heat exchange unit having at least one tube having a multi-layer coating. The multi-layer coating includes a melt flowable copolymer of tetrafluoroethylene adhered to the interior surface or exterior surface of the tube.
Claims13
A process for treating a water stream produced in the recovery of heavy oil from geological formations comprising:
- a) injecting steam or warm water underground into a geological formation containing hydrocarbons and establishing a steam chamber;
- b) transferring heat from said steam chamber to said formation and mobilizing hydrocarbons for extraction from said formation;
- c) extracting said mobilized hydrocarbons from said formation and said hydrocarbons forming an emulsion with a portion of condensed water formed from said steam;
- d) separating mobilized hydrocarbons as a heavy oil product from said hydrocarbon-water emulsion to produce a water stream containing foulants that include residual hydrocarbons and solids;
- e) passing said water stream through a heat exchange unit comprising at least one tube wherein said tube has a multi-layer coating comprising a melt flowable copolymer of tetrafluoroethylene adhered to the interior surface or exterior surface of said tube, wherein said multi-layer coating is adhered to the interior surface or exterior surface of said tube by applying a primer layer to the surface of said tube;
- disposing an overcoat on top of said primer layer, wherein said overcoat comprises multiple layers including a lower layer and an upper layer and wherein said upper layer has an exterior anti-stick surface consisting essentially of baked perfluoropolymer;
- and
- f) removing said foulants from said water stream while altering the temperature of said water stream as said water stream passes through said heat exchange unit;
- wherein said multi-layer coating provides an anti-stick surface that reduces the deposition of foulants, on the interior or exterior surface of said tube as compared to the surface of said tube without said multi-layer coating being present, so as to avoid loss of efficiency in heat transfer and pluggage of said heat exchange unit.
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Dependencies are inferred from the claim text.