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US 8,575,384 B2Granted
Silanol-containing triarylamine derivatives
AssigneeShin-Etsu Chemical Co., Ltd.
InventorsYusuke Itoh, Ayumu Kiyomori
Life of this patent
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Abstract
Provided are triarylamine derivatives excellent in compatibility with various organic solvents or resins, capable of forming a silicon-oxygen bond on the surface of an inorganic material, and allowing easy purification; a preparation process of the triarylamine derivative; an intermediate product of the triarylamine derivative; an inorganic composite material obtained by bonding the triarylamine derivative to the surface of an inorganic material; and a preparation process of the inorganic composite material.
Claims8
A silanol-containing triarylamine derivative represented by formula (1):
- wherein, R1 to R15 each independently represents a substituent selected from diarylamino groups represented by formula (2), linear, branched or cyclic monovalent hydrocarbon groups (which may contain the diarylamino group represented by the formula (2) as a substituent) having from 1 to 20 carbon atoms selected from the group consisting of:
- methyl, ethyl, propyl, isopropyl, butyl, pentyl, hexyl, heptyl, octyl, nonyl, decyl, isobutyl, tert-butyl, cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, vinyl, allyl, propenyl, butenyl;
- phenyl, tolyl;
- 2-phenylethyl, 3-phenylpropyl, and 4-phenylbutyl, alkoxy groups having from 1 to 20 carbon atoms, aryloxy groups having from 6 to 20 carbon atoms, halogen atoms, a hydrogen atom, and an amino group, with the proviso that at least one of R1, R4, R6, R9, R11, and R14 is a substituent represented by the following formula:
- SiR16R17OH wherein, R16 and R17 each independently represents a linear, branched, or cyclic monovalent hydrocarbon group having from 1 to 20 carbon atoms selected from the group consisting of methyl, ethyl, propyl, isopropyl, butyl, pentyl, hexyl, heptyl, octyl, nonyl, decyl, isobutyl, tert-butyl, cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, vinyl, allyl, propenyl, butenyl;
- phenyl, tolyl;
- 2-phenylethyl, 3-phenylpropyl, and 4-phenylbutyl,
- wherein, R21, R23, R25, R26, R28, and R30 each independently represents a substituent selected from linear, branched, or cyclic monovalent hydrocarbon groups having from 1 to 20 carbon atoms selected from the group consisting of:
- methyl, ethyl, propyl, isopropyl, butyl, pentyl, hexyl, heptyl, octyl, nonyl, decyl, isobutyl, tert-butyl, cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, vinyl, allyl, propenyl, butenyl;
- phenyl, tolyl;
- 2-phenylethyl, 3-phenylpropyl, and 4-phenylbutyl, alkoxy groups having from 1 to 20 carbon atoms, aryloxy groups having from 6 to 20 carbon atoms, halogen atoms, a hydrogen atom, and an amino group;
- R22, R24, R27, and R29 each independently represents a substituent selected from linear, branched, or cyclic monovalent hydrocarbon groups having from 1 to 20 carbon atoms selected from the group consisting of:
- methyl, ethyl, propyl, isopropyl, butyl, pentyl, hexyl, heptyl, octyl, nonyl, decyl, isobutyl, tert-butyl, cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, vinyl, allyl, propenyl, butenyl;
- phenyl, tolyl;
- 2-phenylethyl, 3-phenylpropyl, and 4-phenylbutyl, alkoxy groups having from 1 to 20 carbon atoms, aryloxy groups having from 6 to 20 carbon atoms, halogen atoms, a hydrogen atom, an amino group, and substituents represented by SiR16R17OH;
- with the proviso that without R25 and R26, carbon atoms at ortho positions with respect to the nitrogen atom may be coupled to form a carbazole ring structure.
13 more elements
Dependencies are inferred from the claim text.