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US 8,574,790 B2Granted
Fuel cell electrodes with graded properties and method of making
AssigneeGM Global Technology Operations LLC
InventorsPuneet K. Sinha, Balasubramanian Lakshmanan, Scott C. Moose, Nalini Subramanian
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Abstract
A graded electrode is described. The graded electrode includes a substrate; and at least two electrode layers on the substrate forming a combined electrode layer, a composition of the at least two electrode layers being different, the combined electrode layer having an average level of the property that changes across the substrate. Fuel cells using graded electrodes and methods of making graded electrodes are also described.
Claims7
A method of making a graded electrode, the method comprising:
- depositing a first electrode ink on a substrate to form a first electrode layer having a first ionomer to carbon ratio, wherein the substrate is a gas diffusion media or a polymer electrolyte membrane;
- passing the substrate with the first electrode layer under a first blade having a first height at one end applied adjacent to a first side of the substrate and a second height at an opposite end applied adjacent to a second side of the substrate across from the first side, the first height of the first blade being less than the second height of the first blade, to remove a portion of the first electrode layer such that the thickness of the first electrode layer increases across the width of the substrate from the first side of the substrate to the second side of the substrate;
- depositing a second electrode ink adjacent to the first electrode layer to form a second electrode layer having a second ionomer to carbon ratio different from the first ionomer to carbon ratio;
- and
- passing the substrate with the first and second electrode layers under a second blade having a first height at one end applied adjacent to the first side of the substrate and a second height at an opposite end applied adjacent to the second side of the substrate, the first height of the second blade being greater than the second height of the second blade, to remove a portion of the second layer such that the thickness of the second electrode layer decreases across the width of the substrate from the first side of the substrate to the second side of the substrate, a combined electrode layer formed from the first electrode layer and the second electrode layer having an average ionomer to carbon ratio that varies across the width of the substrate from the first side to the second side.
2 more elements
A method of making a graded electrode, the method comprising:
- depositing a first electrode ink on a substrate to form a first electrode layer having a first ionomer to carbon ratio and a thickness that is uniform across a width of the substrate, wherein the substrate is a gas diffusion media or a polymer electrolyte membrane;
- removing a portion of the first electrode layer such that the thickness of the first electrode layer increases across the width of the substrate from a first side of the substrate to a second side of the substrate across from the first side of the substrate;
- wherein the portion of the first electrode layer is removed by passing the substrate with the first electrode layer under a first slanted blade having a first height at one end applied adjacent to the first side of the substrate and a second height at an opposite end applied adjacent to the second side of the substrate, the first height of the first slanted blade being less than the second height of the first slanted blade;
- depositing a second electrode ink over the first electrode layer after the portion of the first electrode layer is removed to form a second electrode layer having a second ionomer to carbon ratio different from the first ionomer to carbon ratio;
- removing a portion of the second electrode layer to form an even upper surface of the second electrode layer, such that the thickness of the second electrode layer decreases across the width of the substrate from the first side of the substrate to the second side of the substrate;
- wherein the portion of the second electrode layer is removed by passing the substrate with the first electrode layer and the second electrode layer under a second slanted blade having a first height at one end applied adjacent to the first side of the substrate and a second height at an opposite end applied adjacent to the second side of the substrate, the first height of the second slanted blade being greater than the second height of the second slanted blade;
- whereby a combined electrode layer formed from the first electrode layer and the second electrode layer has an average ionomer to carbon ratio that varies across the width of the substrate from the first side of the substrate to the second side of the substrate.
4 more elements
Dependencies are inferred from the claim text.