# US 8,570,459 B2 · Light diffusing film, polarizing plate, liquid crystal display device and production method of light diffusing film > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 8,570,459 B2 - Document ID: US8570459B2 - Status: Granted - Kind: B2 - Application number: 13/200,707 - Filed: 2011-09-29 - Published: 2012-04-05 - Granted: 2013-10-29 - Earliest claimed: 2010-09-30 - Assignees: FUJIFILM Corporation - Applicants: Kenichi Fukuda; Jun Watanabe; Yusuke Ohashi - Inventors: Kenichi Fukuda; Jun Watanabe; Yusuke Ohashi - Web page: https://patentgrep.com/patent/US8570459B2 ## CPC - B29D 11/00798: {Producing diffusers} - G02B 1/105 - G02B 1/14: Protective coatings, e.g. hard coatings - G02B 5/0242: {by means of dispersed particles} - G02B 5/3025: {Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state (G02B5/3008, G02B5/3016 take precedence)} - G02F 1/133607: {the light controlling member including light directing or refracting elements, e.g. prisms or lenses} - B29D: PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE (making granules B29B9/00; making preforms B29B11/00) - G02B: OPTICAL ELEMENTS, SYSTEMS OR APPARATUS - G02F: OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS ## Abstract A light diffusing film contains a thermoplastic resin as the main component and contains, in the thermoplastic resin, at least one kind of a light-transmitting particle having an average primary particle diameter of 3 to 10 μm, wherein the absolute value of the refractive index difference between the thermoplastic resin and the light-transmitting particle is from 0.01 to 0.06, wherein one surface has concavoconvex shape, the total haze value is from 15 to 30%, the internal haze value is from 5 to 25%, the surface haze value is from 5 to 20%, and the average film thickness is from 20 to 200 μm. ## Claims ### Claim 1 A liquid crystal display device, comprising: a liquid crystal display element, and a backlight structure for irradiating the liquid crystal display element, wherein the backlight structure includes at least two prism sheets having a large number of fine prism grooves on the liquid crystal display element-side surface, the angle between the groove direction of the prism groove of the two prism sheets and the repeating direction of pixels in the liquid crystal element is 4 to 86°, the two prism sheets are disposed by arranging the groove directions of prism grooves to run at right angles to one another, and a light diffusing film is provided between said two prism sheets and the liquid crystal element, the light diffusing film comprising a thermoplastic resin as the main component and containing, in the thermoplastic resin, at least one kind of a light-transmitting particle having an average primary particle diameter of 3 to 10 μm, wherein the absolute value of the refractive index difference between the thermoplastic resin and the light-transmitting particle is from 0.01 to 0.06, one surface has a concavoconvex shape, the total haze value is from 15 to 30%, the internal haze value is from 5 to 25%, the surface haze value is from 5 to 20%, and the average film thickness is from 20 to 200 μm. ### Claim 2 (depends on 1) The liquid crystal display device having the light diffusing film as claimed in claim 1, wherein the total haze value is from 20 to 30%, the internal haze is from 10 to 20%, and the surface haze is from 10 to 20%. ### Claim 3 (depends on 1) The liquid crystal display device having the light diffusing film as claimed in claim 1, wherein the absolute value of the refractive index difference between the thermoplastic resin and the light-transmitting particle is from 0.01 to 0.03. ### Claim 4 (depends on 1) The liquid crystal display device having the light diffusing film as claimed in claim 1, wherein the average primary particle diameter of the light-transmitting particle is from 5 to 8 μm. ### Claim 5 (depends on 1) The liquid crystal display device having the light diffusing film as claimed in claim 1, wherein the arithmetic average roughness Ra and the average spacing between peaks over the evaluation length Sm, based on JIS B0601, of the surface concavoconvex shape satisfy the following (formula 1) and (formula 2), respectively: 0.10 μm≦Ra≦0.30 μm (formula 1) 50 μm≦Sm≦200 μm (formula 2). ### Claim 6 (depends on 1) The liquid crystal display device having the light diffusing film as claimed in claim 1, wherein the arithmetic average roughness Ra and the average spacing between peaks over the evaluation length Sm, based on JIS B0601, of the surface concavoconvex shape satisfy the following (formula 1′) and (formula 2′), respectively: 0.16 μm≦Ra≦0.24 μm (formula 1′) 60 μm≦Sm≦130 μm (formula 2′). ### Claim 7 (depends on 1) The liquid crystal display device having the light diffusing film as claimed in claim 1, wherein the thermoplastic resin is a cellulose ester. ### Claim 8 (depends on 1) The liquid crystal display device having the light diffusing film as claimed in claim 1, wherein the light diffusing film has a region extending over an entire surface thereof and which is substantially absent of the light-transmitting particle having an average primary particle diameter of 3 to 10 μm, and the region has a thickness of 5 to 30 μm in the thickness direction from the surface having concavoconvex shape. ### Claim 9 (depends on 8) The liquid crystal display device having the light diffusing film as claimed in claim 8, wherein the light-transmitting particle having an average primary particle diameter of 3 to 10 μm is substantially absent in the region of 0 to 20 μm in the thickness direction from the surface opposite to the surface having concavoconvex shape. ### Claim 10 (depends on 1) The liquid crystal display device having the light diffusing film as claimed in claim 1, which is used for a polarizing plate protective film on the backlight side of the liquid crystal display device. ### Claim 11 (depends on 1) A polarizing plate having a polarizing film and a protective film provided on at least one side of the polarizing film, wherein the protective film is the light diffusing film of the liquid crystal display device as claimed in claim 1. ### Claim 12 (depends on 1) A method for producing the light diffusing film of the liquid crystal display device as claimed in claim 1, comprising simultaneously or sequentially casting, in order, on a support to form a film: a light-transmitting particle-containing dope A containing at least one kind of a thermoplastic resin and at least one kind of a light-transmitting particle having an average primary particle diameter of 3 to 10 μm, wherein the absolute value of the refractive index difference between the thermoplastic resin and the light-transmitting particle is from 0.01 to 0.06, and a surface profile-adjusting dope B containing at least one kind of a thermoplastic resin and substantially free from a particle having a particle diameter of 1 μm or more, the surface profile-adjusting dope being lower in the concentration of the thermoplastic resin than the light-transmitting particle-containing dope. ### Claim 13 (depends on 12) The production method of the light diffusing film of the liquid crystal display device as claimed in claim 12, wherein a dope C containing at least one kind of a thermoplastic resin and substantially free from a particle having a particle diameter of 1 μm or more, the light-transmitting particle-containing dope A and the surface profile-adjusting dope B are, in order, simultaneously or sequentially cast on a support to form a film.