# US 8,570,038 B2 · Long range detection of explosives or contraband using nuclear quadrupole resonance > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 8,570,038 B2 - Document ID: US8570038B2 - Status: Granted - Kind: B2 - Application number: 12/957,893 - Filed: 2010-12-01 - Published: 2012-06-28 - Granted: 2013-10-29 - Earliest claimed: 2010-01-29 - Assignees: R.A. Miller Industries, Inc. - Applicants: Paul A. Zank; Peter A. Ketteridge; John T. Apostolos; Candice L. Brittain - Inventors: Paul A. Zank; Peter A. Ketteridge; John T. Apostolos; Candice L. Brittain - Web page: https://patentgrep.com/patent/US8570038B2 ## CPC - G01R 33/12: Measuring magnetic properties of articles or specimens of solids or fluids (involving magnetic resonance G01R33/20) - G01N 24/084: {Detection of potentially hazardous samples, e.g. toxic samples, explosives, drugs, firearms, weapons} - G01R 33/441: {Nuclear Quadrupole Resonance [NQR] Spectroscopy and Imaging} - G01V 3/14: operating with electron or nuclear magnetic resonance - G01R 33/3453: {Transverse electromagnetic [TEM] coils} - G01R 33/3607: {RF waveform generators, e.g. frequency generators, amplitude-, frequency- or phase modulators or shifters, pulse programmers, digital to analog converters for the RF signal, means for filtering or attenuating of the RF signal} - G01R: MEASURING ELECTRIC VARIABLES; MEASURING MAGNETIC VARIABLES (indicating correct tuning of resonant circuits H03J3/12) - G01N: INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES (measuring or testing apparatus or processes other than immunoassay, involving enzymes or microorganisms C12M, C12Q) - G01V: GEOPHYSICS; GRAVITATIONAL MEASUREMENTS; DETECTING MASSES OR OBJECTS; TAGS (means for indicating the location of accidentally buried, e.g. snow-buried, persons A63B29/02) ## Abstract Nuclear quadrupole resonance substance detection at a distance is provided by crossed or overlapping high frequency beams in which the frequency of one of the beams is offset with respect to the frequency of the other beam by an amount equal to the resonant frequency of the non-linear material to be detected. The presence of energy at the offset frequency within the overlapping beams pumps any non-linear material within the overlapping beams to cause stimulated emission which is detected, in one embodiment, utilizing a network analyzer, along with correlation of the detected stimulated emission signature with a library of signatures for predetermined substances. ## Claims ### Claim 1 Apparatus for long distance detection of a substance utilizing nuclear quadrupole resonance, comprising: at least one antenna for projecting two overlapping high frequency beams towards a given area; a pair of transmitters, one of said transmitters operating at a first frequency and the second of said transmitters operating at a different offset frequency, the offset being that associated with the resonant frequency of the substance to be detected, said transmitters being coupled to said at least one antenna; a receive antenna tuned to the resonant frequency of the substance; a cross product modulation detector coupled to said receive antenna for detecting the cross product modulation product corresponding to the resonant frequency of the corresponding substance; and, an explosive/contraband detector coupled to said cross product modulation detector for detecting a stimulated emission response of any of said substance in the overlapped beams, said explosive/contraband detector coupled to a signature library such that correlation between the stimulated response signature and at least one signature in the signature library is detected, such that if said substance exists in said crossed beams, the existence thereof will be ascertained. ### Claim 2 (depends on 1) The apparatus of claim 1, wherein said substance includes a non-linear material. ### Claim 3 (depends on 1) The apparatus of claim 1, wherein said at least one antenna is a directional antenna. ### Claim 4 (depends on 3) The apparatus of claim 3, wherein said at least one directional antenna includes a microwave dish. ### Claim 5 (depends on 1) The apparatus of claim 1, and further including a coding module between the outputs of one of said transmitters and said antenna for superimposing a code on the signal transmitted therefrom. ### Claim 6 (depends on 5) The apparatus of claim 5, and further including a decoding module coupled between said cross product modulation detector and said explosive/contraband detector. ### Claim 7 (depends on 6) The apparatus of claim 6, wherein said coding module and said decoding module are provided with identical codes, thereby to provide signal processing gain. ### Claim 8 (depends on 1) The apparatus of claim 1, wherein said explosive/contraband detector includes a network analyzer having an S21 output and wherein said stimulated emission response is measured in terms of said S21 output. ### Claim 9 (depends on 1) The apparatus of claim 1, and further including an amplitude modulation detector coupled to said receive antenna and substituted for said cross product modulation detector, said amplitude modulation detector coupled to said explosive/contraband detector. ### Claim 10 (depends on 9) The apparatus of claim 9, and further including a coding module between one of said transmitters and said at least one antenna and a decoding module coupled between said amplitude modulation detector and said explosive/contraband detector. ### Claim 11 (depends on 1) The apparatus of claim 1, wherein said at least one antenna includes two directional antennas that project crossing beams at a distance therefrom, said pair of transmitters being coupled to said directional antennas, whereby the existence of said substance in the area of the crossed beams can be ascertained. ### Claim 12 (depends on 1) The apparatus of claim 1, wherein said at least one antenna includes a single directional antenna, both of said transmitters being coupled to the input of said single antenna, said antenna providing two co-located beams which overlap along the length thereof. ### Claim 13 (depends on 1) The apparatus of claim 1, wherein said pair of transmitters include a frequency synthesizer, a frequency-stepped network analyzer coupled to said frequency synthesizer, said frequency synthesizer outputting clock pulses to said network analyzer, said network analyzer utilizing said clock pulses generate a stepped set of frequencies at which stimulated emissions are expected to occur; a single sideband up converter coupled to said frequency synthesizer and network analyzer for outputting a signal corresponding to the fundamental f0 output of said frequency synthesizer and said f0 fundamental frequency plus the output signal of said stepped network analyzer, thus to output a frequency of f0 plus the frequency from said stepped network analyzer; a summing network coupled to said single sideband and up converter and said frequency synthesizer to output the f0 fundamental frequency of said frequency synthesizer and the f0 fundamental frequency plus the output frequency of said stepped network analyzer; and, an amplifier coupled to the summing network for amplifying the signal from said summing network, said amplifier being coupled to said at least one antenna. ### Claim 14 (depends on 13) The apparatus of claim 13, wherein said receive antenna is coupled town input of said network analyzer, the output of said stepped network analyzer being an S21 ratio indicative of the detection of stimulated emissions from said substance. ### Claim 15 (depends on 14) The apparatus of claim 14, and further including allow noise amplifier coupled between said receive antenna and said stepped network analyzer. ### Claim 16 (depends on 1) The apparatus of claim 1, wherein high frequency signals generated from said transmitters are in the gigahertz frequency range and wherein said offset is in the megahertz frequency range. ### Claim 17 (depends on 16) The apparatus of claim 16, wherein said megahertz frequency range is between 0.1 MHz and 5 MHz.