# US 8,569,628 B2 · Insulated wire

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- Number: US 8,569,628 B2
- Document ID: US8569628B2
- Status: Granted
- Kind: B2
- Application number: 12/870,329
- Filed: 2010-08-27
- Published: 2011-08-11
- Granted: 2013-10-29
- Earliest claimed: 2010-02-10
- Assignees: Hitachi Cable, Ltd.; Hitachi Magnet Wire Corp.
- Applicants: Tomiya Abe; Takanori Yamazaki; Kiyoshi Watanabe; Hideyuki Kikuchi; Takahiko Hanada; Daisuke Hino
- Inventors: Tomiya Abe; Takanori Yamazaki; Kiyoshi Watanabe; Hideyuki Kikuchi; Takahiko Hanada; Daisuke Hino
- Web page: https://patentgrep.com/patent/US8569628B2

## CPC

- H01B 3/301: {Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen or carbon in the main chain of the macromolecule, not provided for in group H01B3/302}
- H01B 3/305: {Polyamides or polyesteramides}
- H01B 3/441: {from alkenes}
- H01B 3/445: {from vinylfluorides or other fluoroethylenic compounds}
- H01B: CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES (selection for magnetic properties H01F1/00; waveguides H01P {; printed circuits H05K})

## Abstract

There is provided an insulated wire having an insulation film composed of a plurality of layers provided on a conductor, in which: the insulation film includes a first film layer and a second film layer; the first film layer is made of a first resin composition formed by graft-polymerizing a graft compound with an ethylene-tetrafluoroethylene copolymer and is provided on a circumference of the conductor; and the second film layer is made of a second resin composition being a polymer alloy made of a polyphenylene sulfide resin and a polyamide resin, or being a polymer alloy made of a polyether ether ketone resin and a polyamide resin and is provided on a circumference of the first film layer.

## Claims

### Claim 1

An insulated wire to be used for a coil for electrical equipment controlled by an inverter having an insulation film composed of a plurality of layers provided on a conductor, wherein:
the plurality of layers comprises a first film layer and a second film layer;
the first film layer is made of a first resin composition formed by graft-polymerizing a graft compound with an ethylene-tetrafluoroethylene copolymer and is provided on a circumference of the conductor;
the second film layer is made of a second resin composition being a polymer alloy made of a polyether ether ketone resin and a polyamide resin and is provided on a circumference of the first film layer;
the storage elastic modulus of the second resin composition is 1 GPa or more at 20° C., and 10 MPa or more at 200° C.;
the insulated wire has a partial-discharge start voltage of 1500 V or more and is configured to be used for a coil for electrical equipment controlled by an inverter; and
the insulated wire has an adhesion property that, when a five-coil worth length of insulated wire is wound onto a winding rod having a diameter equivalent to a diameter of the conductor, and inspected for abnormalities selected from the group consisting of cracks, flaws, wrinkles and peeling an optical microscope at a magnification of 50, the insulation film does not exhibit any of said abnormalities.

### Claim 2 (depends on 1)

The insulated wire according to claim 1, wherein:
the graft compound contains a peroxide group or an organic group having an α,β-unsaturated double bond at the terminal end thereof to be working as a graft-polymerization bonding group, and also contains at least one of the functional groups providing adhesion selected from a carboxyl group, carboxylic acid anhydride residue, epoxy group, and hydrolyzable silyl group.

### Claim 3 (depends on 1)

The insulated wire according to claim 1, wherein:
a thickness of the first film layer is 30 μm or more but not thicker than 300 μm; and a thickness of the second film layer is 20 μm or more but not thicker than 300 μm.

### Claim 4 (depends on 1)

The insulated wire according to claim 1, wherein the insulated wire has a wear resistance property such that a number of reciprocations of a sensing pin perpendicularly applied to a surface of the insulation film under a load of 5.9 N until an electric current begins to flow between the sensing pin and an electrode connected to the conductor is more that 2000.

### Claim 5

An insulated wire to be used for a coil for electrical equipment controlled by an inverter having an insulation film composed of a plurality of layers provided on a conductor, wherein:
the insulation film comprises a first film layer and a second film layer;
the first film layer is made of a first resin composition formed by graft-polymerizing a graft compound with an ethylene-tetrafluoroethylene copolymer and is provided on a circumference of the conductor;
the second film layer is made of a second resin composition being a polymer alloy made of a polyphenylene sulfide resin and a polyamide resin and is provided on a circumference of the first film layer;
the storage elastic modulus of the second resin composition is 1 GPa or more at 20° C., and 10 MPa or more at 200° C.;
the insulated wire has a partial-discharge start voltage of 1500 V or more and is configured to be used for a coil for electrical equipment controlled by an inverter; and
the insulated wire has an adhesion property that, when a five-coil worth length of insulated wire is wound onto a winding rod having a diameter equivalent to a diameter of the conductor, and inspected for abnormalities selected from the group consisting of cracks, flaws, wrinkles and peeling an optical microscope at a magnification of 50, the insulation film does not exhibit any of said abnormalities.

### Claim 6 (depends on 5)

The insulated wire according to claim 5, wherein:
the graft compound contains a peroxide group or an organic group having an α,β-unsaturated double bond at a terminal end thereof to be working as a graft-polymerization bonding group, and also contains at least one of the functional groups providing adhesion selected from a carboxyl group, carboxylic acid anhydride residue, epoxy group, and hydrolyzable silyl group.

### Claim 7 (depends on 5)

The insulated wire according to claim 5, wherein:
a thickness of the first film layer is 30 μm or more but not thicker than 300 μm; and a thickness of the second film layer is 20 μm or more but not thicker than 300 μm.

### Claim 8 (depends on 5)

The insulated wire according to claim 5, wherein the insulated wire has a wear resistance property such that a number of reciprocations of a sensing pin perpendicularly applied to a surface of the insulation film under a load of 5.9 N until an electric current begins to flow between the sensing pin and an electrode connected to the conductor is more that 2000.
