# US 8,569,442 B2 · Hydrogenation process for improving yield of hydrogenated bisphenol-A-based epoxy resin

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- Number: US 8,569,442 B2
- Document ID: US8569442B2
- Status: Granted
- Kind: B2
- Application number: 13/023,610
- Filed: 2011-02-09
- Published: 2012-04-26
- Granted: 2013-10-29
- Earliest claimed: 2010-10-25
- Assignees: Nan Ya Plastics Corporation
- Applicants: Dein-Run Fung; Jung-Jen Chuang; Chia-Ruey Tsai
- Inventors: Dein-Run Fung; Jung-Jen Chuang; Chia-Ruey Tsai
- Web page: https://patentgrep.com/patent/US8569442B2

## CPC

- B01J 19/0066: {Stirrers (mixing per se B01F)}
- B01J 19/18: Stationary reactors having moving elements inside (B01J19/08, B01J19/26 take precedence)
- C08G 59/24: carbocyclic
- B01J 2219/00083: Coils
- B01J 2219/00085: Plates; Jackets; Cylinders
- B01J: CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- C08G: MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS

## Abstract

A hydrogenation process for hydrogenating bisphenol-A-based epoxy resin under low-temperature, low-pressure conditions includes using a hydrogenation reactor that has a gas-distributing agitator functional to introduce and exhaust hydrogen gas and stir liquid reactant, so that hydrogen gas introduced into the hydrogenation reactor can be evenly distributed into a liquid reactant placed into the hydrogenation reactor to make the liquid reactant contain a high level of dissolved hydrogen, which not only enhances activity of an involved hydrogenation catalyst and accelerates hydrogenation reaction, but also allows hydrogenation reaction to be performed in a low-temperature, low-pressure environment. The hydrogenation process improve yield of the hydrogenated bisphenol-A-based epoxy resin to 99.0-99.9%, while significantly reducing building and maintaining costs for the hydrogenation reactor, thus being an economic process.

## Claims

### Claim 1

A hydrogenation process for improving yield of hydrogenated bisphenol-A-based epoxy resin, comprising steps of:
a) providing a column-shaped hydrogenation reactor required to have a height/diameter ratio ranging between 0.4 and 3 for hydrogenating a liquid reactant placed therein and further comprise a heat exchange plate or a cooling coil for timely removing heat generated in the course of hydrogenation reaction and a gas-distributing agitator internally equipped in the reactor and comprising a hollow shaft thereof and blades at a terminal of the hollow shaft for introducing and exhausting hydrogen gas to the liquid reactant and simultaneously stirring the liquid reactant if started;
b) introducing a liquid reactant containing bisphenol-A-based epoxy resin prepared in a solvent into the hydrogenation reactor;
c) adding a hydrogenation catalyst selected one from ruthenium, palladium, platinum, rhodium or nickel in an amount ranging between 0.5 and 5 wt % by weight of the bisphenol-A-based epoxy resin into the liquid reactant of step b);
d) introducing hydrogen gas having a pressure ranging between 360 and 735 lb/in2 into the hydrogenation reactor
e) activating the gas-distributing agitator rotated in a predetermined rotation rate to have the hydrogen gas drawn into the hollow shaft of the gas-distributing agitator through gas inlets formed on the hollow shaft and located above a liquid surface of the liquid reactant, and further have the drawn hydrogen gas exhausted out through gas outlets formed on the hollow shaft and immersed in the liquid reactant, thereby the rotating blades of the gas-distributing agitator evenly distributing the exhausted hydrogen gas over the liquid reactant;
f) performing hydrogenation reaction at a reaction temperature ranging between 80 and 90° C. for a reaction time ranging between 1 and 18 hours; and
g) at completion of the hydrogenation reaction, cooling the liquid reactant to the room temperature, filtering out the catalyst and removing the solvent to obtain hydrogenated bisphenol-A-based epoxy resins with a yield ranging between 99.0 and 99.9%.

### Claim 2 (depends on 1)

The hydrogenation process of claim 1, wherein the solvent used at step b) is methylbenzene, methyl isobutyl ketone or tetrahydrofuran.

### Claim 3 (depends on 1)

The hydrogenation process of claim 1, wherein the hydrogenation reaction is performed at the temperature of 80° C.