Nonaqueous electrolyte solution and lithium secondary battery using same
AssigneeUbe Industries, Ltd.
InventorsKoji Abe, Kazuhiro Miyoshi, Chisen Hashimoto, Masahide Kondo
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Abstract
The present invention provides a nonaqueous electrolytic solution in which an electrolyte salt is dissolved in a nonaqueous solvent, containing 0.01% to 30% by weight of a 1,2-cyclohexanediol derivative having a specific structure; and a lithium secondary battery using the nonaqueous electrolytic solution. The lithium secondary battery exhibits excellent battery characteristics such as electrical capacity, cycle property, and storage property and can maintain excellent long-term battery performance.
Claims21
A nonaqueous electrolytic solution wherein an electrolyte salt is dissolved in a nonaqueous solvent, comprising 0.01% to 30% by weight of at least one compound selected from the group consisting of 1,2-cyclohexanediol cyclic sulfite, hexahydro-1,3,2-benzodioxathiol-2,2-dioxide, and 1,2-cyclohexanediol derivatives represented by the following general formula (X), on the basis of the weight of the nonaqueous electrolytic solution:
- wherein R1 to R10 each independently represent a hydrogen atom, a C1 to C12 alkyl group, a C2 to C12 alkenyl group, a C2 to C12 alkynyl group, a C6 to C18 aryl group, or a C1 to C12 alkoxy group, and may bond to each other to form a ring structure, and any hydrogen atom of R1 to R10 may be substituted by a halogen atom, with the proviso that the case where all of R1 to R10 are hydrogen atoms is excluded;
- and X represents a >S═O group or a >C═O group.
A lithium secondary battery comprising a positive electrode, a negative electrode, and a nonaqueous electrolytic solution in which an electrolyte salt is dissolved in a nonaqueous solvent, wherein the nonaqueous electrolytic solution comprises 0.01% to 30% by weight of at least one compound selected from the group consisting of 1,2-cyclohexanediol cyclic sulfite, hexahydro-1,3,2-benzodioxathiol-2,2-dioxide, and 1,2-cyclohexanediol derivatives represented by the general formula (X), on the basis of the weight of the nonaqueous electrolytic solution.
Dependencies are inferred from the claim text.