Process for the continuous production of high purity phenolic glycol ether
AssigneeDow Global Technologies LLC
InventorsMax Tirtowidjojo, Edward D. Daugs
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AssigneeDow Global Technologies LLC
InventorsMax Tirtowidjojo, Edward D. Daugs
Estimating the term…
Phenolic glycol ethers, e.g., ethylene glycol phenyl ether, are prepared by a continuous, nonaqueous process comprising the steps of (A) contacting under isothermal reactive conditions in a first reactor or reaction zone an alkylene oxide, e.g., ethylene oxide, with (i) a stoichiometric molar excess of a phenolic compound, e.g., phenol, and (ii) a catalytic amount of a base, e.g., sodium hydroxide, homogeneously dispersed throughout the phenolic compound, to form a first intermediate phenolic glycol ether product, (Bj transferring the first intermediate phenolic glycol ether product to a second reactor or reaction zone, and (C) subjecting the first intermediate phenolic glycol ether product to adiabatic reactive conditions in the second reactor or reaction zone to form a second intermediate phenolic glycol ether product comprising phenolic glycol ether, unreacted phenolic compound, catalyst, water and byproduct glycols. In addition, the mono-/di-product weight ratio can be adjusted by increasing or decreasing the amount of base catalyst employed.
A continuous, nonaqueous process for producing phenolic glycol ether, the process comprising the steps of (A) contacting under isothermal reactive conditions in a first reactor or reaction zone an alkylene oxide with (i) a stoichiometric molar excess of a phenolic compound, and (ii) a catalytic amount of a base homogeneously dispersed throughout the phenolic compound, to form a first intermediate phenolic glycol ether product, (B) transferring the first intermediate phenolic glycol ether product to a second reactor or reaction zone, and (C) subjecting the first intermediate phenolic glycol ether product to adiabatic reactive conditions at an exit temperature greater than that of step (A) in the second reactor or reaction zone to form a second intermediate phenolic glycol ether product comprising phenolic glycol ether, unreacted phenolic compound, catalyst, water and byproduct glycols, wherein the phenolic glycol ether comprises mono-alkyl phenolic glycol ether and di-alkyl glycol phenolic ether and the ratio of mono-alkyl phenolic glycol ether to di-alkyl glycol phenolic ether is determined by the amount of the base.
A method for adjusting the mono-/di-alkyl phenolic glycol ether product weight ratio of a product comprising mono-alkyl phenolic glycol ether and di-alkyl glycol phenolic ether, the product produced by a process comprising the step of contacting under nonaqueous reactive conditions at least one phenol, at least one alkylene oxide and at least one basic homogeneous catalyst, the method comprising the step of increasing the concentration of the catalyst to increase the mono-/di-product weight ratio or decreasing the concentration of the catalyst to decrease the mono-/di-product weight ratio.
Dependencies are inferred from the claim text.