Oligomerized ester alkoxylate compositions
AssigneeDow Global Technologies LLC
InventorsDaniele Vinci, Jochem Kersbulck
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Abstract
A process results in oligomerized ester alkoxylate compositions having substantially no unsaturation, which may be useful as lubricants, heat transfer fluids, plasticizers, thickening agents, surfactants, or power transmission fluids. The steps include, in either order, oligomerization of a hydroxylated fatty acid or fatty ester and quantitative reaction of unreacted carboxylic acid or ester groups with an alcohol, with the product of either reaction then being alkoxylated in the presence of a double metal cyanide catalyst. These oligomerized ester alkoxylates may be derived from vegetable oils to ensure high levels of renewable carbons. The compositions may exhibit desirably high viscosity index, low pour point, and high levels of renewable carbons.
Claims8
A process to prepare an oligomerized ester alkoxylate comprising
- preparing an oligomerized ester by either
- (a) partially oligomerizing 12-hydroxy stearic acid or 12-hydroxy stearic acid methyl ester such that less than 99 mole percent of the carboxylic acid groups or ester groups is reacted to form a product including an oligomer of the hydroxylated fatty acid or the hydroxylated fatty ester having unreacted carboxylic acid groups or ester groups;
- and quantitatively reacting the unreacted carboxylic acid groups or ester groups with an alcohol having from 2 to 22 carbon atoms;
- optionally removing any excess alcohol;
- to form a product including an oligomerized ester of the hydroxylated fatty acid or of the hydroxylated fatty ester;
- or
- (b) quantitatively reacting 12-hydroxy stearic acid or 12-hydroxy stearic acid methyl ester with an alcohol having from 2 to 22 carbon atoms;
- optionally removing any excess alcohol;
- to form a product including an ester of the 12-hydroxy stearic acid or 12-hydroxy stearic acid methyl ester;
- and partially oligomerizing the produced ester such that less than 99 mole percent of the carboxylic acid groups or ester groups is reacted to form a product including an oligomerized ester of 12-hydroxy stearic acid or 12-hydroxy stearic acid methyl ester;
- and
- reacting the oligomerized ester with an alkylene oxide, in the presence of a double metal cyanide catalyst, under conditions such that an oligomerized ester alkoxylate is formed.
Dependencies are inferred from the claim text.