Process for preparing EU-1 zeolite
AssigneeIfp Energies Nouvelles
InventorsSimone Goergen, Loïc Rouleau, Joël Patarin
Life of this patent
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Abstract
The invention concerns a process for preparing an EU-1 zeolite having a XO2/Y2O3 ratio in the range 10 to 100, comprising the following steps: a) mixing, in an aqueous medium, at least one source of at least one oxide XO2, X being selected from silicon and/or germanium, at least one source of at least one oxide Y2O3, Y being selected from aluminium, iron, gallium and boron, and at least one organic template Q; b) drying the reaction mixture derived from step a) at a temperature of less than 200° C.; c) hydrothermal treatment of the dried reaction mixture derived from step b) in an autoclave, said dried reaction mixture not being in contact with a liquid phase at the bottom of the autoclave.
Claims19
A process for preparing an EU-1 zeolite having a XO2/Y2O3 ratio in the range 10 to 100, comprising:
- a) mixing, in an aqueous medium, at least one source of at least one oxide XO2, X being silicon and/or germanium, at least one source of at least one oxide Y2O3, Y being aluminium, iron, gallium and boron, and at least one organic template Q, said reaction mixture having the following molar composition:
- XO2/Y2O3
- 10 to 100;
- OH−/XO2
- 0.1 to 6.0;
- (M+ + Q)/Y2O3
- 0.5 to 100;
- Q/(M+ + Q)
- 0.1 to 1;
- H2O/XO2
- 1 to 100;
- M+/XO2
- 0 to 0.15;
- where M+represents an alkali metal or ammonium monovalent cation;
- b) drying the reaction mixture derived from a) at a temperature of less than 200° C.;
- c) hydrothermal treatment of the dried reaction mixture derived from b) in an autoclave, said dried reaction mixture not being in contact with a liquid phase at the bottom of the autoclave, whereby EU-1 zeolite is produced.
A process for preparing an EU-1 zeolite having a XO2/ Y2O3 ratio of 10-100, comprising hydrothermal treatment of the product of drying an aqueous mixture at a temperature of less than 200° C., said product comprising of at least one source of at least one oxide XO2, X being silicon and/or germanium, at least one source of at least one oxide Y2 O 3 , Y being aluminium, iron, gallium or boron, and at least one organic template Q, and having the following molar composition:
- XO2/Y2O3
- 10 to 100;
- OH−/XO2
- 0.1 to 6.0;
- (M+ + Q)/Y2O3
- 0.5 to 100;
- Q/(M+ + Q)
- 0.1 to 1;
- H2O/XO2
- 1 to 100;
- M+/XO2
- 0 to 0.2;
- where M+represents an alkali metal or ammonium monovalent cation.
Dependencies are inferred from the claim text.