Nonwoven webs having improved barrier properties

A laminate having alcohol repellency properties, the laminate comprising:

• a first spunbond web;
• a second spunbond web;
• a meltblown web between the first spunbond web and the second spunbond web, wherein the first spunbond web, the meltblown web, and the second spunbond web are bonded together to form the laminate such that the first spunbond web defines a first surface and the second spunbond web defines a second surface;
• a metalized layer on the first surface of the first spunbond web;
• and
• a fluorinated polymeric coating attached to the metalized layer such that the metalized layer is between the first spunbond web and the fluorinated polymeric coating, wherein the fluorinated polymeric coating comprises a perfluoroalkyl(alkyl) (meth)acrylate monomer polymerized on the surface of the spunbond web via exposure to a low frequency energy source, wherein the perfluoroalkyl(alkyl) (meth)acrylate monomer has a perfluoroalkyl side groups comprising —(CF2)z—F, where z is an integer from 1 to 6, wherein the fluorinated polymeric coating further comprises a comonomer, the comonomer comprising a diacrylic fluoroalkyl monomer;
• wherein the laminate has an alcohol repellency of greater than 80%.

A laminate having alcohol repellency properties, the laminate comprising:

• a first spunbond web;
• a second spunbond web;
• a meltblown web between the first spunbond web and the second spunbond web, wherein the first spunbond web, the meltblown web, and the second spunbond web are bonded together to form the laminate such that the first spunbond web defines a first surface and the second spunbond web defines a second surface;
• a metalized layer on the first surface of the first spunbond web;
• and a fluorinated polymeric coating attached to the metalized layer such that the metalized layer is between the first spunbond web and the fluorinated polymeric coating, wherein the fluorinated polymeric coating comprises a perfluoroalkyl(alkyl) (meth)acrylate monomer polymerized on the surface of the spunbond web via exposure to a low frequency energy source, wherein the perfluoroalkyl(alkyl) (meth)acrylate monomer has a perfluoroalkyl side groups comprising —(CF2)—F, where z is an integer from 1 to 6 wherein the fluorinated polymeric coating further comprises a comonomer having the structure:
• where n is an integer 2 to 12;
• wherein the laminate has an alcohol repellency of greater than 80%.