# US 8,543,242 B2 · Method and apparatus for managing volatile organic content in polyolefin > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 8,543,242 B2 - Document ID: US8543242B2 - Status: Granted - Kind: B2 - Application number: 13/552,470 - Filed: 2012-07-18 - Published: 2012-11-08 - Granted: 2013-09-24 - Earliest claimed: 2006-08-25 - Assignees: Chevron Phillips Chemical Company LP - Applicants: Timothy O. Odi - Inventors: Timothy O. Odi - Web page: https://patentgrep.com/patent/US8543242B2 ## CPC - C08F 6/003: {from polymer solutions, suspensions, dispersions or emulsions without recovery of the polymer therefrom} - B29B 7/72: Measuring, controlling or regulating - B29B 7/748: {Plants (B29B7/7433, B29B7/7485, B29B7/7495 take precedence)} - B29B 7/845: {Venting, degassing or removing evaporated components in devices with rotary stirrers} - B29B 7/88: Adding charges {, i.e. additives} - B29B 7/94: Liquid charges - B29B 9/065: {under-water, e.g. underwater pelletizers} - B29B 7/48: with intermeshing devices, e.g. screws - C08F: MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS - B29B: PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS ## Abstract The present invention relates generally to polyolefin production and to reducing volatile organic content (VOC) associated with the polyolefin. Techniques include the construction and implementation of a purge column model to calculate or estimate the VOC content in the polyolefin exiting the purge column. The techniques facilitate the design and operation of the polyolefin manufacturing process. ## Claims ### Claim 1 A polyolefin production system comprising: a polymerization reactor configured to polymerize olefin monomer in a hydrocarbon diluent in the presence of a catalyst to produce a product slurry comprising polyolefin particles and hydrocarbon; and a separator vessel configured to separate flashed hydrocarbon from the product slurry to generate a flash gas stream and a recovered polyolefin stream; a purge column configured to purge the recovered polyolefin stream comprising the polyolefin particles and residual hydrocarbon with a purge gas to generate a discharge stream comprising a first portion of the residual hydrocarbon and the purge gas and a polyolefin product stream comprising the polyolefin particles and a second portion of the residual hydrocarbon; a computer configured to calculate an estimated value representing a volatile organic content (VOC) of the polyolefin product stream based on a flow rate of the polyolefin particles flowing through the purge column and a flow rate of the purge gas flowing through the purge column; and a control feature configured to adjust an operating condition of the polyolefin production system based on the estimated value representing the VOC. ### Claim 2 (depends on 1) The polyolefin production system of claim 1, wherein the purge column comprises a countercurrent purge column. ### Claim 3 (depends on 1) The polyolefin production system of claim 1, wherein the computer is configured to estimate the value representing the VOC by iteratively driving a difference in flow values for material flow to and from the purge column to zero for all components of the purge column. ### Claim 4 (depends on 1) The polyolefin production system of claim 1, wherein the polymerization reactor comprises a continuous take-off configured to discharge the product slurry from the polymerization reactor. ### Claim 5 (depends on 1) The polyolefin production system of claim 1, comprising a controller configured to adjust a residence time of the polyolefin particles in the purge column based on the estimated value representing the VOC. ### Claim 6 (depends on 1) The polyolefin production system of claim 1, comprising a controller configured to adjust a flow rate of the purge gas entering the purge column based on the estimated value representing the VOC. ### Claim 7 (depends on 1) The polyolefin production system of claim 1, comprising a controller configured to adjust a temperature setting for the polyolefin particles in the purge column based on the estimated value representing the VOC. ### Claim 8 (depends on 1) The polyolefin production system of claim 1, comprising processing components configured to process the polyolefin particles to form a polyolefin product. ### Claim 9 (depends on 1) The polyolefin production system of claim 1, wherein the computer is configured to estimate the value representing the VOC by iteratively driving a difference in flow values for material flow to and from the purge column to zero for all components of the purge column. ### Claim 10 (depends on 1) The polyolefin production system of claim 1, comprising: a first flow path from the purge column configured to pass the discharge stream generated by the purge column; and a second flow path from the purge column configured to pass the polyolefin product stream, wherein the second portion of the residual hydrocarbon of the polyolefin product stream comprises the VOC of the polyolefin product stream. ### Claim 11 (depends on 1) The polyolefin production system of claim 1, wherein the control feature is configured to adjust an operating condition of the purge column based on the estimated value representing the VOC. ### Claim 12 (depends on 1) The polyolefin production system of claim 1, wherein the polymerization reactor comprises a continuous take-off configured to discharge the product slurry from the polymerization reactor. ### Claim 13 (depends on 1) The polyolefin production system of claim 1, wherein the polymerization reactor comprises a settling leg configured to discharge the product slurry from the polymerization reactor. ### Claim 14 A polyolefin production system, comprising: a polymerization reactor configured to polymerize olefin monomer in a hydrocarbon diluent in the presence of a catalyst to produce a product slurry comprising polyolefin particles and hydrocarbon; and a separator vessel configured to separate flashed hydrocarbon from the product slurry to generate a flash gas stream and a recovered polyolefin stream; a purge column configured to receive a purge gas and configured to purge the recovered polyolefin stream comprising the polyolefin particles and residual hydrocarbon with the purge gas; a first flow path from the purge column configured to pass a discharge stream generated by the purge column, the discharge stream comprising a first portion of the residual hydrocarbon and the purge gas; a second flow path from the purge column configured to pass a polyolefin product stream comprising the polyolefin particles and a second portion of the residual hydrocarbon, wherein the second portion comprises a volatile organic content (VOC) of the polyolefin product stream; a computer configured to calculate an estimated value representing the VOC of the polyolefin product stream based on a flow rate of the polyolefin particles flowing through the purge column and a flow rate of the purge gas flowing through the purge column; and a control feature configured to adjust an operating condition of the polyolefin production system based on the estimated value representing the VOC. ### Claim 15 A polyolefin production system comprising: a polymerization reactor configured to polymerize olefin monomer in a hydrocarbon diluent in the presence of a catalyst to produce a product slurry comprising polyolefin particles and hydrocarbon; a separator vessel configured to separate flashed hydrocarbon from the product slurry to generate a flash gas stream and a recovered polyolefin stream, a purge column configured to purge the recovered polyolefin stream with a purge gas, the recovered polyolefin stream comprising the polyolefin particles and residual hydrocarbon; a first flow path configured to pass a discharge stream generated by the purge column, the discharge stream comprising a first portion of the residual hydrocarbon and the purge gas; a second flow path configured to pass a polyolefin product stream generated by the purge column comprising the polyolefin particles and a second portion of the residual hydrocarbon; and a computer configured to calculate an estimated value representing a volatile organic content (VOC) of the polyolefin product stream based on a flow rate of the polyolefin particles flowing through the purge column and a flow rate of the purge gas flowing through the purge column; and a control feature configured to adjust an operating condition of the polyolefin production system based on the estimated value representing the VOC.