# US 8,542,355 B2 · Light amplifying devices for surface enhanced raman spectroscopy

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- Number: US 8,542,355 B2
- Document ID: US8542355B2
- Status: Granted
- Kind: B2
- Application number: 13/383,078
- Filed: 2009-07-08
- Published: 2012-05-10
- Granted: 2013-09-24
- Earliest claimed: 2009-07-08
- Assignees: Hewlett-Packard Development Company, L.P.
- Applicants: David A. Fattal; Jingjing Li; Zhiyong Li; Shih-Yuan Wang
- Inventors: David A. Fattal; Jingjing Li; Zhiyong Li; Shih-Yuan Wang
- Web page: https://patentgrep.com/patent/US8542355B2

## CPC

- G01N 21/658: {enhancement Raman, e.g. surface plasmons}
- B82Y 20/00: Nanooptics, e.g. quantum optics or photonic crystals
- G01N: INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES (measuring or testing apparatus or processes other than immunoassay, involving enzymes or microorganisms C12M, C12Q)
- B82Y: SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES

## Abstract

A light amplifying device for surface enhanced Raman spectroscopy is disclosed herein. The device includes a dielectric layer having two opposed surfaces. A refractive index of the dielectric layer is higher than a refractive index of a material or environment directly adjacent thereto. At least one opening is formed in one of the two opposed surfaces of the dielectric layer, and at least one nano-antenna is established on the one of the two opposed surfaces of the dielectric layer. A gain region is positioned in the dielectric layer or adjacent to another of the two opposed surfaces of the dielectric layer.

## Claims

### Claim 1

A light amplifying device for surface enhanced Raman spectroscopy, comprising:
a dielectric layer having two opposed surfaces, wherein a refractive index of the dielectric layer is higher than a refractive index of a material or environment directly adjacent thereto;
at least one opening formed in one of the two opposed surfaces of the dielectric layer;
at least one nano-antenna established on the one of the two opposed surfaces of the dielectric layer; and
a gain region positioned in the dielectric layer or adjacent to an other of the two opposed surfaces of the dielectric layer.

### Claim 2 (depends on 1)

The light amplifying device as defined in claim 1, further comprising a substrate having the dielectric layer established directly or indirectly thereon, wherein the substrate has a refractive index that is less than the refractive index of the dielectric layer.

### Claim 3 (depends on 2)

The light amplifying device as defined in claim 2 wherein the gain region is positioned in the dielectric layer, and wherein the dielectric layer is established directly on the substrate.

### Claim 4 (depends on 2)

The light amplifying device as defined in claim 2 wherein the gain region is positioned adjacent to the other of the two opposed surfaces of the dielectric layer, and wherein the gain region is established directly on the substrate.

### Claim 5 (depends on 1)

The light amplifying device as defined in claim 1 wherein the gain region includes at least one of quantum dots or quantum wells.

### Claim 6 (depends on 1)

The light amplifying device as defined in claim 1 wherein the gain region includes a III-IV semiconductor material or erbium doped glass.

### Claim 7 (depends on 1)

The light amplifying device as defined in claim 1, further comprising at least one of i) a pair of electrodes or ii) a light source configured to supply energy to the gain region.

### Claim 8

A system for performing surface enhanced Raman spectroscopy, comprising:
a light amplifying device, including:
a dielectric layer having two opposed surfaces, wherein a refractive index of the dielectric layer is higher than a refractive index of a material or environment adjacent thereto;
at least one opening formed in one of the two opposed surfaces of the dielectric layer;
at least one nano-antenna established on the one of the two opposed surfaces of the dielectric layer; and
a gain region positioned in the dielectric layer or adjacent to an other of the two opposed surfaces of the dielectric layer;
an energy source operatively configured to supply energy to the gain region; and
a light source operatively configured to direct light toward the at least one nano-antenna of the light amplifying device.

### Claim 9 (depends on 8)

The system as defined in claim 8, further comprising a detector operatively positioned to detect an enhanced Raman signal from a material of interest positioned adjacent to at least a portion of the at least one nano-antenna of the light amplifying device.

### Claim 10 (depends on 8)

The system as defined in claim 8 wherein the light amplifying device further includes a substrate having the dielectric layer established directly or indirectly thereon, wherein the substrate has a refractive index that is less than the refractive index of the dielectric layer.

### Claim 11 (depends on 10)

The system as defined in claim 10 wherein the gain region is positioned in the dielectric layer, and wherein the dielectric layer is established directly on the substrate.

### Claim 12 (depends on 10)

The system as defined in claim 10 wherein the gain region is positioned adjacent to the other of the two opposed surfaces of the dielectric layer, and wherein the gain region is established directly on the substrate.

### Claim 13

A method for making a light amplifying device for surface enhanced Raman spectroscopy, the method comprising:
forming at least one opening in one of two opposed surfaces of a dielectric layer having a refractive index that is higher than a refractive index of a material or environment configured to be directly adjacent thereto;
establishing at least one nano-antenna on the one of the two opposed surfaces of the dielectric layer; and
establishing a gain region in the dielectric layer or adjacent to an other of the two opposed surfaces of the dielectric layer.

### Claim 14 (depends on 13)

The method as defined in claim 13, further comprising operatively positioning an energy source such that it is selectively configured to supply energy to the gain region, the energy source being selected from i) a pair of electrodes; and ii) a light source.

### Claim 15 (depends on 13)

The method as defined in claim 13, further comprising establishing the dielectric layer directly or indirectly on a substrate having a refractive index that is less than the refractive index of the dielectric layer.

### Claim 16 (depends on 15)

The method as defined in claim 15 wherein the establishing of the gain region in the dielectric layer and the establishing of the dielectric layer directly on the substrate are accomplished by:
growing a first portion of the dielectric layer directly on the substrate;
growing quantum wells to form the gain region on the first portion of the dielectric layer; and
growing a second portion of the dielectric layer on the gain region, wherein a surface of the second portion of the dielectric layer is the one of the two opposed surfaces of the dielectric layer.

### Claim 17 (depends on 15)

The method as defined in claim 15 wherein the establishing of the gain region adjacent to the other of the two opposed surfaces is accomplished by:
depositing a material that forms the gain region directly on the substrate; and then
depositing the dielectric layer on the gain region.

### Claim 18 (depends on 15)

The method as defined in claim 15 wherein the establishing of the gain region in the dielectric layer is accomplished via ion implantation.
