# US 8,542,333 B2 · Liquid crystal cell alignment surface programming method and liquid cell light modulator devices made thereof > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 8,542,333 B2 - Document ID: US8542333B2 - Status: Granted - Kind: B2 - Application number: 13/054,224 - Filed: 2009-07-14 - Published: 2011-05-19 - Granted: 2013-09-24 - Earliest claimed: 2008-07-14 - Assignees: Universite Laval - Applicants: Tigran Galstian - Inventors: Tigran Galstian - Web page: https://patentgrep.com/patent/US8542333B2 ## CPC - G02F 1/133711: {by organic films, e.g. polymeric films} - G02F 1/1303: {Apparatus specially adapted to the manufacture of LCDs} - G02F 1/133726: {made of a mesogenic material} - G02F 1/133749: {for low pretilt angles, i.e. lower than 15 degrees} - G02F 1/133765: {without a surface treatment} - G02F 1/133788: {by light irradiation, e.g. linearly polarised light photo-polymerisation} - G02F 2203/12: spatial light modulator - G02F: OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS ## Abstract A liquid crystal display or other light modulator is provide with an alignment layer with a pretilt that is better than is currently available with rubbing technology. The liquid crystal cell consumes less electrical power to operate. The pretilt can be programmed using suitable field and recorded in the alignment layer. ## Claims ### Claim 1 A liquid crystal cell comprising: a control field source; and a pair of cell walls defining a cavity, the cavity being filled for operation with nematic liquid crystal molecules, at least one of the cell walls having an alignment layer including a rubbed foundation layer and an ordered surface layer that interacts with the liquid crystal molecules to cause alignment of the liquid crystal molecules in a zero field ground state in a predetermined essentially uniform pre-tilt director orientation between 7° and 30°, the control field source being configured to cause a change in orientation of said liquid crystal molecules from said ground state to change optical properties of said cell; wherein the ordered surface layer is formed, over said foundation layer having a pre-tilt angle between 1° and 6°, with alignment liquid crystal molecules aligned using an external programming field at an orientation between 7° and 30° without mechanical rubbing, said external programming field being at least one of an electric, magnetic and acoustic field. ### Claim 2 (depends on 1) The cell as defined in claim 1, wherein said ordered surface layer is programmed while in contact with liquid crystal molecules, said programming field being used to align said liquid crystal molecules that in turn cause alignment of molecules of said ordered surface layer prior to curing. ### Claim 3 (depends on 2) The cell as defined in claim 2, wherein said ordered surface layer is programmed while in contact with said liquid crystal molecules in said cell. ### Claim 4 (depends on 1) The cell walls as defined in claim 1, wherein said surface layer contains particles or surface molecules which provide angular correlation with said liquid crystal molecules. ### Claim 5 (depends on 1) The cell walls as defined in claim 1, wherein said surface material of the cell wall preferably allows a partial interdiffusion with said liquid crystal molecules prior to curing. ### Claim 6 (depends on 1) The cell as defined in claim 1, wherein said ordered surface layer comprises polymer molecules subjected to polymerization after being aligned using said programming field. ### Claim 7 (depends on 1) The cell as defined in claim 1, wherein said ordered surface layer comprises molecules subjected to solidification after being aligned using said programming field while in an orientationally and spatially mobile state. ### Claim 8 (depends on 1) The cell as defined in claim 1, wherein said surface layer contains surface molecules or particles which may be oriented prior to the injection of said liquid crystal molecules. ### Claim 9 (depends on 1) The cell as defined in claim 1, wherein said surface layer contains surface molecules or particles which may be oriented and fixed prior to the injection of said liquid crystal molecules. ### Claim 10 (depends on 8) The cell as defined in claim 8, wherein said particles have anisotropic magnetic properties. ### Claim 11 (depends on 2) The cell as defined in claim 2, wherein at least one additive is added to said liquid crystal molecules to enhance an efficiency of said field programming and/or stabilizing. ### Claim 12 (depends on 8) The cell as defined in claim 8, wherein said surface molecules are photo-alignable molecules dispersed in said surface layer. ### Claim 13 (depends on 1) The cell as defined in claim 1, wherein said programming field is electric. ### Claim 14 (depends on 1) The cell as defined in claim 1, wherein said control field is electric, thermal or magnetic. ### Claim 15 (depends on 1) The cell as defined in claim 1, wherein said liquid crystal mixture contains particles or molecules that may be aligned by means of said control field source prior of programming the said surface layer. ### Claim 16 (depends on 1) The cell as defined in claim 1, wherein said liquid crystal mixture contains molecules that may be polymerized and attached to the said surface layer after being reoriented by the said control field source. ### Claim 17 (depends on 16) The cell as defined in claim 16, wherein said liquid crystal mixture contains inhibitors to minimize the volume polymerization while said surface layer contains initiators allowing the polymerization to take place near to the surface layer attaching the created network to said surface layer. ### Claim 18 (depends on 1) The cell as defined in claim 1, wherein said cell walls are free of a rubbed substrate layer. ### Claim 19 (depends on 1) The cell as defined in claim 1, wherein said cell is a spatial light modulator. ### Claim 20 A method of manufacturing a liquid crystal cell, comprising: using an external programming field to form, over a rubbed foundation layer having a pre-tilt angle between 1° and 6°, an ordered surface layer with aligned molecules on at least one wall of a cavity of said cell, wherein said aligned molecules of said ordered surface layer are ordered and stabilized using an external programming field at an orientation between 7° and 30° without mechanical rubbing and when in contact with liquid crystal molecules of said cell cause alignment of the liquid crystal molecules in a zero control field ground state in a predetermined essentially uniform pre-tilt director orientation between 7° and 30°, said programming field being at least one of an electric, magnetic and acoustic field. ### Claim 21 (depends on 20) The method as defined in claim 20, wherein said aligned molecules are cured, said alignment of the liquid crystal molecules in said zero control field ground state being different from an alignment of said aligned molecules prior to curing. ### Claim 22 (depends on 1) The cell as defined in claim 1, wherein said ordered surface layer causes zero-field ground state alignment of the liquid crystal molecules at a predetermined essentially uniform pre-tilt director orientation between 8° and 16°, preferably 10°.