Palladium catalyst and process for production of bisaryl compound using same
AssigneeNiigata University
InventorsHisahiro Hagiwara, Norio Tsubokawa
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Abstract
Disclosed are: a novel palladium catalyst which does not undergo leakage, can be recycled, does not require the use of any phosphorus-containing ligand, and has a high catalytic activity; and a process for producing a novel bisaryl compound using the palladium catalyst. In the production of a bisaryl compound by reacting an aromatic halide with an aromatic boronic acid in the presence of a palladium catalyst and a base, the palladium catalyst comprises a dendrimer containing a silica particle as a core and a palladium compound dissolved in an ionic liquid and supported on the dendrimer.
Claims7
A method for producing a bisaryl compound, using a palladium catalyst when producing the bisaryl compound by reacting an aromatic halide with an aromatic boronic acid in the presence of the palladium catalyst and a base, wherein the palladium catalyst comprises a palladium compound dissolved in an ionic liquid and supported on a dendrimer containing a silica particle as a core, wherein the dendrimer is represented in the following formula, wherein R1, R2 is selected from hydrogen and methyl group
Dependencies are inferred from the claim text.