# US 8,540,949 B2 · Apparatus for hydroprocessing hydrocarbons

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- Number: US 8,540,949 B2
- Document ID: US8540949B2
- Status: Granted
- Kind: B2
- Application number: 13/168,078
- Filed: 2011-06-24
- Published: 2012-11-22
- Granted: 2013-09-24
- Earliest claimed: 2011-05-17
- Assignees: Uop LLC
- Applicants: Andrew P. Wieber; Joao J. da Silva Ferreira Alves
- Inventors: Andrew P. Wieber; Joao J. da Silva Ferreira Alves
- Web page: https://patentgrep.com/patent/US8540949B2

## CPC

- C10G 65/14: plural parallel stages only
- C10G 65/12: including cracking steps and other hydrotreatment steps
- C10G 65/16: including only refining steps
- C10G 65/18: including only cracking steps
- C10G 2300/4081: Recycling aspects
- C10G 2300/42: Hydrogen of special source or of special composition
- C10G: CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION (cracking to hydrogen or synthesis gas C01B; cracking or pyrolysis of hydrocarbon gases to individual hydrocarbons or mixtures thereof of definite or specified constitution C07C; cracking to cokes C10B); RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES

## Abstract

An apparatus and process is disclosed for hydroprocessing hydrocarbon feed in a hydroprocessing unit and hydrotreating a second hydrocarbon. A warm separator sends vaporous hydrotreating effluent to be flashed with liquid hydroprocessing effluent to produce a vapor flash overhead that can be recycled to the hydrotreating unit to provide hydrogen requirements.

## Claims

### Claim 1

An apparatus for hydroprocessing hydrocarbons comprising:
a hydrocracking reactor in communication with a first hydrogen line and a first hydrocarbon feed line for hydrocracking a hydrocarbon feed stream to lower boiling hydrocarbons transported in a hydrocracking effluent line;
a cold separator in communication with the hydrocracking reactor for providing a vaporous hydrocracking effluent stream comprising hydrogen in an overhead line and a liquid hydrocracking effluent stream in a bottoms line;
a hydrotreating reactor in communication with a second hydrogen line for hydrotreating a second hydrocarbon feed stream to produce a hydrotreating effluent stream;
a warm separator in communication with the hydrotreating reactor for separating the hydrotreating effluent stream into a vaporous hydrotreating effluent stream comprising hydrogen in a warm overhead line and a liquid hydrotreating effluent stream in a warm bottoms line, wherein the bottoms line of the cold separator is joined with the warm overhead line of the warm separator; and
a fractionation section in downstream communication with the hydrocracking reactor for fractionating the hydrocracking effluent stream and the hydrotreating reactor being in downstream communication with the fractionation section.

### Claim 2 (depends on 1)

The apparatus of claim 1 wherein said first hydrogen line is in downstream communication with two compressor stages.

### Claim 3 (depends on 1)

The apparatus of claim 1 further comprising a diesel line carrying a diesel stream produced by said fractionation section and said second hydrocarbon feed line being the diesel line.

### Claim 4 (depends on 1)

The apparatus of claim 1 wherein said first hydrogen line is in communication with said overhead line of said cold separator.

### Claim 5 (depends on 1)

The apparatus of claim 1 further comprising a supplemental hydrogen line in communication with said second hydrogen line.

### Claim 6 (depends on 1)

The apparatus of claim 1 further comprising a hot separator in communication with the hydrocracking reactor for providing a vaporous hydrocarbonaceous stream in a hot overhead line and a liquid hydrocarbonaceous stream in a hot bottoms line and the cold separator in communication with the hot overhead line of the hot separator.

### Claim 7 (depends on 1)

The apparatus of claim 1 further comprising a fractionation column in communication with the warm bottoms line of the warm separator for fractionating at least a portion of the liquid hydrotreating effluent stream to provide a low sulfur diesel stream.

### Claim 8 (depends on 1)

The apparatus of claim 1 further comprising a cold flash drum in communication with the bottoms line of the cold separator, the cold flash drum having a flash overhead line for carrying a cold flash vapor stream and the cold flash drum having a flash bottoms line in communication with a fractionation column in the fractionation section.

### Claim 9 (depends on 8)

The apparatus of claim 8 wherein said hydrotreating reactor is in communication with said overhead line of said cold flash drum.

### Claim 10 (depends on 9)

The apparatus of claim 9 further comprising a recycle compressor in communication with said overhead line of said cold flash drum.

### Claim 11 (depends on 1)

The apparatus of claim 1 further comprising a first compressor in communication with a make-up hydrogen line for compressing a make-up hydrogen stream to provide a first compressed make-up hydrogen stream in a first compressed make-up hydrogen line; a split in communication with said first compressor for splitting said first compressed make-up hydrogen stream into a first portion in a first split line and a second portion in a second split line; a second compressor in communication with said first split line for compressing said first portion of said first compressed make-up hydrogen stream to provide a second compressed make-up hydrogen stream in a second compressed make-up hydrogen line; said hydrocracking reactor in communication with said first split line; and said a hydrotreating reactor in communication with said second split line.

### Claim 12

An apparatus for producing diesel comprising:
a hydrocracking reactor in communication with a first hydrogen line and a hydrocarbon feed line for hydrocracking a hydrocarbon feed stream to lower boiling hydrocarbons transported in a hydrocracking effluent line;
a hydrotreating reactor in communication with a second hydrogen line for hydrotreating a diesel stream to produce low sulfur diesel in a hydrotreating effluent stream;
a cold separator in communication with the hydrocracking reactor for providing a vaporous hydrocracking effluent stream comprising hydrogen in an overhead line and the liquid hydrocracking effluent stream in a bottoms line; and
a warm separator in direct communication with the hydrotreating reactor for separating the hydrotreating effluent stream into a vaporous hydrotreating effluent stream comprising hydrogen in a warm overhead line and a liquid hydrotreating effluent stream in a warm bottoms line;
wherein the bottoms line of the cold separator is in communication with the overhead line of the warm separator.

### Claim 13 (depends on 12)

The apparatus of claim 12 further comprising a cold flash drum in communication with the bottoms line of the cold separator, the cold flash drum having a flash overhead line for carrying a cold flash vapor stream in communication with said hydrotreating reactor and the cold flash drum having a flash bottoms line in communication with a fractionation section.

### Claim 14 (depends on 13)

The apparatus of claim 13 further comprising a recycle compressor in communication with said flash overhead line of said cold flash drum.

### Claim 15 (depends on 12)

The apparatus of claim 12 further comprising a recycle compressor in communication with said overhead line of said cold separator.

### Claim 16 (depends on 12)

The apparatus of claim 12 further comprising a first compressor in communication with a make-up hydrogen line for compressing a make-up hydrogen stream to provide a first compressed make-up hydrogen stream in a first compressed make-up hydrogen line; a split in communication with said first compressor for splitting said first compressed make-up hydrogen stream into a first portion in a first split line and a second portion in a second split line; a second compressor in communication with said first split line for compressing said first portion of said first compressed make-up hydrogen stream to provide a second compressed make-up hydrogen stream in a second compressed make-up hydrogen line; said hydrocracking reactor in communication with said first split line; and said a hydrotreating reactor in communication with said second split line.

### Claim 17

An apparatus for producing diesel comprising:
a hydrocracking reactor in communication with a first hydrogen line and a hydrocarbon feed line for hydrocracking a hydrocarbon feed stream to lower boiling hydrocarbons transported in a hydrocracking effluent stream line;
a hydrotreating reactor in communication with a second hydrogen line and the hydrocracking reactor for hydrotreating a diesel stream to produce low sulfur diesel in a hydrotreating effluent stream;
a cold separator in communication with the hydrocracking reactor for providing a vaporous hydrocracking effluent stream comprising hydrogen in an overhead line and a liquid hydrocracking effluent stream in a bottoms line, wherein said hydrocracking reactor is in communication with said overhead line of said cold separator;
a warm separator in communication with the hydrotreating reactor for separating the hydrotreating effluent stream into a vaporous hydrotreating effluent stream comprising hydrogen in a warm overhead line and a liquid hydrotreating effluent stream in a warm bottoms line; and
a cold flash drum in communication with the warm separator, the cold flash drum having a flash overhead line for carrying a cold flash vapor stream in communication with said hydrotreating reactor and the cold flash drum having a flash bottoms line in communication with a fractionation section,
wherein the hydrotreating reactor is in downstream communication with the fractionation section via a diesel line carrying the diesel stream produced by said fractionation section.

### Claim 18 (depends on 17)

The apparatus of claim 17 wherein said cold flash drum is in communication with a warm overhead line of said warm separator and said bottoms line of said cold separator.
