# US 8,540,901 B2 · Aqueous fluororesin dispersion and method for producing the same

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- Number: US 8,540,901 B2
- Document ID: US8540901B2
- Status: Granted
- Kind: B2
- Application number: 13/314,237
- Filed: 2011-12-08
- Published: 2012-03-29
- Granted: 2013-09-24
- Earliest claimed: 2006-06-29
- Assignees: Daikin Industries, Ltd.
- Applicants: Chie Sawauchi; Nobuhiko Tsuda
- Inventors: Chie Sawauchi; Nobuhiko Tsuda
- Web page: https://patentgrep.com/patent/US8540901B2

## CPC

- C08J 3/03: in aqueous media
- C09D 127/18: Homopolymers or copolymers of tetrafluoroethene
- C08J 2327/12: containing fluorine atoms
- C08J: WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H (working, e.g. shaping, of plastics B29)
- C09D: COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR (cosmetics A61K; processes for applying liquids or other fluent materials to surfaces, in general, B05D; staining wood B27K5/02; glazes or vitreous enamels C03C; natural resins, French polish, drying-oils, driers, turpentine, per se, C09F; polishing compositions other than French polish, ski waxes C09G; adhesives or use of materials as adhesives C09J; materials for sealing or packing joints or covers C09K3/10; materials for stopping leaks C09K3/12; processes for the electrolytic or electrophoretic production of coatings C25D)

## Abstract

The present invention provides an aqueous fluororesin dispersion comprising a melt-processable fluororesin which is low in fluorinated surfactant concentration and excellent in dispersion stability even when the concentration of the melt-processable fluororesin is high. The present invention is related to an aqueous fluororesin dispersion comprising a melt-processable fluororesin particle dispersed in an aqueous medium, wherein a concentration of the melt-processable fluororesin is 55 to 75% by mass relative to the aqueous fluororesin dispersion, and a fluorinated surfactant content in the aqueous fluororesin dispersion is not higher than a level corresponding to 100 ppm of the melt-processable fluororesin.

## Claims

### Claim 1

A method for producing an aqueous fluororesin dispersion,
wherein a crude aqueous fluororesin dispersion comprising a melt-processable fluororesin particle dispersed in an aqueous medium is subjected to a treatment in contact with an ion exchange resin and a concentration by phase separation in the presence of an electrolyte and/or a nonfluorinated anionic emulsifier to thereby obtain the aqueous fluororesin dispersion,
wherein the crude aqueous fluororesin dispersion is brought into contact with the ion exchange resin,
and then, after the step of adding the electrolyte and/or the nonfluorinated anionic emulsifier, the concentration by phase separation is carried out,
wherein the electrolyte is at least one selected from the group consisting of sulfuric acid, succinic acid, carbonic acid, and salts thereof, and
wherein the nonfluorinated anionic emulsifier is one such that a 0.1% (by mass) aqueous solution thereof has a surface tension of not higher than 60 mN/m.

### Claim 2 (depends on 1)

The method for producing the aqueous fluororesin dispersion according to claim 1,
wherein the electrolyte and/or nonfluorinated anionic emulsifier is added in an amount corresponding to 10 to 10000 ppm of the melt-processable fluororesin.

### Claim 3 (depends on 1)

The method for producing the aqueous fluororesin dispersion according to claim 1,
wherein the concentration by phase separation is carried out in the presence of the electrolyte in an amount corresponding to 10 to 10000 ppm of the melt-processable fluororesin and/or the nonfluorinated anionic emulsifier in an amount corresponding to 10 to 10000 ppm of the melt-processable fluororesin.

### Claim 4 (depends on 1)

The method for producing the aqueous fluororesin dispersion according to claim 1,
wherein a concentration of the melt-processable fluororesin after concentration by the phase separation step is 55 to 75% by mass relative to the aqueous fluororesin dispersion, and
a fluorinated surfactant content in the aqueous fluororesin dispersion is not higher than a level corresponding to 100 ppm of the melt-processable fluororesin.

### Claim 5 (depends on 1)

The method for producing the aqueous fluororesin dispersion according to claim 1,
wherein the aqueous fluororesin dispersion has an electric conductivity of not lower than 10 μS/cm.

### Claim 6 (depends on 1)

The method for producing the aqueous fluororesin dispersion according to claim 1,
wherein the melt-processable fluororesin particle has an average primary particle diameter of 10 to 400 nm.