# US 8,540,817 B2 · Method of manufacturing a Si(1-v-w-x)CwAlxNv substrate, method of manufacturing an epitaxial wafer, Si(1-v-w-x)CwAlxNv substrate, and epitaxial wafer

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- Number: US 8,540,817 B2
- Document ID: US8540817B2
- Status: Granted
- Kind: B2
- Application number: 12/989,015
- Filed: 2009-04-17
- Published: 2011-02-17
- Granted: 2013-09-24
- Earliest claimed: 2008-04-24
- Assignees: Sumitomo Electric Industries, Ltd.
- Applicants: Issei Satoh; Michimasa Miyanaga; Shinsuke Fujiwara; Hideaki Nakahata
- Inventors: Issei Satoh; Michimasa Miyanaga; Shinsuke Fujiwara; Hideaki Nakahata
- Web page: https://patentgrep.com/patent/US8540817B2

## CPC

- C30B 23/00: Single-crystal growth by condensing evaporated or sublimed materials
- C23C 14/0617: {AIII BV compounds, where A is Al, Ga, In or Tl and B is N, P, As, Sb or Bi}
- C23C 14/28: by wave energy or particle radiation (C23C14/32 - C23C14/48 take precedence)
- C30B 25/02: Epitaxial-layer growth
- C30B 29/36: Carbides
- C30B 29/38: Nitrides
- C30B 29/403: {AIII-nitrides}
- H10P 14/20: of semiconductor materials
- H10P 14/2905: {Silicon, silicon germanium or germanium}
- H10P 14/3202: {Materials thereof}
- H10P 14/3208: {Silicon carbide}
- H10P 14/3216: {Nitrides}
- H10P 14/3238: {being insulating materials}
- H10P 14/3252: {Alternating layers, e.g. superlattice}
- H10P 14/3256: {Microstructure}
- H10P 14/3416: {Nitrides}
- C30B 25/00: Single-crystal growth by chemical reaction of reactive gases, e.g. chemical vapour-deposition growth
- C30B 28/12: directly from the gas state
- C30B 28/14: by chemical reaction of reactive gases
- Y10T 428/24471: Crackled, crazed or slit
- C30B: SINGLE-CRYSTAL GROWTH (by using ultra-high pressure, e.g. for the formation of diamonds, B01J3/06); UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL (zone-refining of metals or alloys C22B); PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE (casting of metals, casting of other substances by the same processes or devices B22D; working of plastics B29; modifying the physical structure of metals or alloys C21D, C22F); SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE (for producing semiconductor devices or parts thereof H10); APPARATUS THEREFOR
- C23C: COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL (making metal-coated products by extrusion B21C23/22; covering with metal by connecting pre-existing layers to articles, see the relevant places, e.g. B21D39/00, B23K; metallising of glass C03C; metallising mortars, concrete, artificial stone, ceramics or natural stone C04B41/00; enamelling of, or applying a vitreous layer to, metals C23D; treating metal surfaces or coating of metals by electrolysis or electrophoresis C25D; single-crystal film growth C30B; by metallising textiles D06M11/83; decorating textiles by locally metallising D06Q1/04)
- H10P: GENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10
- Y10T: TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION

## Abstract

There are provided a method for manufacturing a Si(1-v-w-x)CwAlxNv substrate having a reduced number of cracks and high processability, a method for manufacturing an epitaxial wafer, a Si(1-v-w-x)CwAlxNv substrate, and an epitaxial wafer. A method for manufacturing a Si(1-v-w-x)CwAlxNv substrate 10a includes the following steps. First, a Si substrate 11 is prepared. A Si(1-v-w-x)CwAlxNv layer (0<v<1, 0<w<1, 0<x<1, and 0<v+w+x<1) is then grown on the Si substrate at a temperature below 550° C.

## Claims

### Claim 1

A method for manufacturing a Si(1-v-w-x)CwAlxNv substrate, comprising the steps of:
preparing a Si substrate; and
growing a Si(1-v-w-x)CwAlxNv layer (0<v<1, 0<w<1, 0<x<1, and 0<v+w+x<1) on the Si substrate at a temperature below 550° C.,
wherein the Si(1-v-w-x)CwAlxNv layer has a composition range 0.001≦v+x≦0.1.

### Claim 2 (depends on 1)

The method for manufacturing a Si(1-v-w-x)CwAlxNv substrate according to claim 1, further comprising the step of removing the Si substrate after the growing step.

### Claim 3 (depends on 1)

The method for manufacturing a Si(1-v-w-x)CwAlxNv substrate according to claim 1, wherein the Si(1-v-w-x)CwAlxNv layer is grown by a pulsed laser deposition method in the growing step.

### Claim 4 (depends on 1)

A method for manufacturing an epitaxial wafer, comprising the steps of:
manufacturing a Si(1-v-w-x)CwAlxNv substrate by a method for manufacturing a Si(1-v-w-x)CwAlxNv substrate according to claim 1; and
growing an Al(1-y-z)GayInzN layer (0≦y≦1, 0≦z≦1, and 0≦y+z≦1) on the Si(1-v-w-x)CwAlxNv layer.
