# US 8,540,816 B2 · Aggregate and filler extracted from slag

> Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt

- Number: US 8,540,816 B2
- Document ID: US8540816B2
- Status: Granted
- Kind: B2
- Application number: 12/376,206
- Filed: 2007-08-10
- Published: 2009-10-22
- Granted: 2013-09-24
- Earliest claimed: 2006-08-10
- Assignees: Sachtleben Chemie GmbH
- Applicants: Djamschid Amirzadeh-Asl
- Inventors: Djamschid Amirzadeh-Asl
- Web page: https://patentgrep.com/patent/US8540816B2

## CPC

- C22B 21/0069: {from scrap, skimmings or any secondary source aluminium, e.g. recovery of alloy constituents (C22B21/0046, C22B21/0053 and C22B21/0092 take precedence)}
- C04B 40/0042: {Powdery mixtures}
- C05D 3/04: from blast-furnace slag or other slags containing lime or calcium silicates
- C21B 3/06: Treatment of liquid slag
- C21C 5/36: Processes yielding slags of special composition
- C22B 7/04: Working-up slag
- C04B 2111/1081: {Chromium VI, e.g. for avoiding chromium eczema}
- C21B 2400/02: Physical or chemical treatment of slags
- Y02P 10/20: Recycling
- Y02W 30/50: Reuse, recycling or recovery technologies
- Y02W 30/91: Use of waste materials as fillers for mortars or concrete
- C22B: PRODUCTION AND REFINING OF METALS (electrolytic C25); PRETREATMENT OF RAW MATERIALS
- C04B: LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE {(roofing granules E04D7/005)}; CERAMICS (devitrified glass-ceramics C03C10/00); REFRACTORIES; TREATMENT OF NATURAL STONE
- C05D: INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
- C21B: MANUFACTURE OF IRON OR STEEL (preliminary treatment of ferrous ores or scrap C22B1/00)
- C21C: PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- Y02P: CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02W: CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT

## Abstract

An aggregate and/or filler extracted from slag, a method for the production thereof, and the use thereof.

## Claims

### Claim 1

A recyclate comprising components obtained during extraction of metals from an aluminum salt slag, which contains up to 3 wt. % nitrides, wherein said recyclate further comprising an iron-sulfate-containing additive.

### Claim 2 (depends on 1)

The recyclate according to claim 1, wherein the nitride is aluminum nitride.

### Claim 3 (depends on 1)

The recyclate according to claim 1, having a chromate solubility of less than 2 mg/kg.

### Claim 4 (depends on 1)

The recyclate of claim 1, containing less than 1.5 wt. % free CaO or free MgO.

### Claim 5 (depends on 1)

The recyclate of claim 1, containing less than 1 wt. % free CaO or free MgO.

### Claim 6 (depends on 2)

The recyclate of claim 2, containing less than 1 wt. % nitrides.

### Claim 7 (depends on 1)

The recyclate according to claim 1, wherein the iron-sulfate-containing additive comprises at least one member selected from the group consisting of iron(II) sulfate, iron(III) sulfate, iron(II)-containing spent sulfuric acids, iron(III)-containing spent sulfuric acids, metal-sulfate-containing iron sulfates, a mixture of iron(II) sulfate heptahydrate and iron(II) sulfate monohydrate, and a mixture of green salt and filter salt.

### Claim 8 (depends on 1)

The recyclate according to claim 1, wherein the iron-sulfate-containing additive is present in an amount of from 0.1 to 95 wt. %.

### Claim 9 (depends on 1)

The recyclate according to claim 1, wherein the grain size of the recyclate is between 0.01 and 64 mm.

### Claim 10 (depends on 1)

The recyclate according to claim 1, wherein that the pH value of the recyclate is adjusted to between 2 and 13.

### Claim 11 (depends on 1)

A process for the production of a recyclate according to claim 1, comprising reacting said slag with an iron-sulfate-containing additive.

### Claim 12 (depends on 11)

A process according to claim 11, wherein the iron-sulfate-containing additive is at least one selected from the group consisting of iron(II) sulfate, iron(III) sulfate, iron(II)-containing spent sulfuric acid, iron(III)-containing spent sulfuric acid, a metal-sulfate-containing iron sulfate, a mixture of iron(II) sulfate heptahydrate and iron(II) sulfate monohydrate, and a mixture of green salt and filter salt.

### Claim 13 (depends on 11)

A process according to claim 11, wherein the iron-sulfate-containing additive is provided as a solution, as moist filter cake or in powder form.

### Claim 14 (depends on 11)

A process according to claim 11, wherein the reaction takes place in a high-speed mixer.

### Claim 15 (depends on 11)

A process according to claim 11, wherein the iron-sulfate-containing additive is present in an amount of from 0.1 to 95 wt. %.

### Claim 16 (depends on 11)

A process according to claim 11, wherein a grain size of the slag is between 0.01 and 64 mm.

### Claim 17 (depends on 11)

A process according to claim 11, wherein the resulting recyclate is dried and granulated or ground.

### Claim 18 (depends on 11)

A process according to claim 11, wherein recyclate is dispersed in water, filtered, and ground to a fine powder or deagglomerated.

### Claim 19 (depends on 1)

A process comprising adding the recyclate of claim 1 in a metallurgic process.

### Claim 20 (depends on 2)

A process for the production of a recyclate according to claim 2, comprising reacting said slag with an iron-sulfate-containing additive.

### Claim 21 (depends on 20)

A process according to claim 20, wherein the iron-sulfate-containing additive is at least one selected from the group consisting of iron(II) sulfate, iron(III) sulfate, iron(II)-containing spent sulfuric acid, iron(III)-containing spent sulfuric acid, a metal-sulfate-containing iron sulfate, a mixture of iron(II) sulfate heptahydrate and iron(II) sulfate monohydrate, green salt and filter salt.

### Claim 22 (depends on 20)

A process according to claim 20, wherein the iron-sulfate-containing additive is provided as a solution, as moist filter cake or in powder form.

### Claim 23 (depends on 20)

A process according to claim 20, wherein the reaction takes place in a high-speed mixer.

### Claim 24 (depends on 20)

A process according to claim 20, wherein the iron-sulfate-containing additive is present in an amount of from 0.1 to 95 wt. %.

### Claim 25 (depends on 20)

A process according to claim 20, wherein a grain size of the slag is between 0.01 and 64 mm.

### Claim 26 (depends on 20)

A process according to claim 20, wherein the resulting recyclate is dried and granulated or ground.

### Claim 27 (depends on 20)

A process according to claim 20, wherein recyclate is dispersed in water, filtered, and ground to a fine powder or deagglomerated.

### Claim 28 (depends on 2)

A process comprising adding the recyclate of claim 2 in a metallurgic process.

### Claim 29 (depends on 1)

The recyclate according to claim 1, having a chromate solubility of less than 2 mg/kg.

### Claim 30 (depends on 1)

The recyclate according to claim 1, further comprising an iron-sulfate-containing additive.

### Claim 31 (depends on 30)

The recyclate according to claim 30, wherein the iron-sulfate-containing additive comprises at least one member selected from the group consisting of iron(II) sulfate, iron(III) sulfate, iron(II)-containing spent sulfuric acids, iron(III)-containing spent sulfuric acids, metal-sulfate-containing iron sulfates, a mixture of iron(II) sulfate heptahydrate and iron(II) sulfate monohydrate, and a mixture of green salt and filter salt.

### Claim 32 (depends on 30)

The recyclate according to claim 30, wherein the iron-sulfate-containing additive is present in an amount of from 0.1 to 95 wt. %.

### Claim 33 (depends on 1)

The recyclate according to claim 1, wherein the grain size of the recyclate is between 0.01 and 64 mm.

### Claim 34 (depends on 1)

The recyclate according to claim 1, wherein the pH value of the recyclate is adjusted to between 2 and 13.
