# US 8,540,794 B2 · Method for reducing iron oxide and producing syngas

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- Number: US 8,540,794 B2
- Document ID: US8540794B2
- Status: Granted
- Kind: B2
- Application number: 11/906,761
- Filed: 2007-10-03
- Published: 2008-04-17
- Granted: 2013-09-24
- Earliest claimed: 2004-09-03
- Applicants: Jiann-Yang Hwang; Xiaodi Huang
- Inventors: Jiann-Yang Hwang; Xiaodi Huang
- Web page: https://patentgrep.com/patent/US8540794B2

## CPC

- C21C 5/567: {operating in a continuous way}
- C21B 13/0046: {making metallised agglomerates or iron oxide}
- C21B 13/08: in rotary furnaces
- C21B 13/105: {Rotary hearth-type furnaces}
- F27B 1/10: Details, accessories or equipment specially adapted for furnaces of these types
- F27B 7/34: Arrangements of heating devices
- F27B 9/16: the charge moving in a circular or arcuate path
- F27B 9/36: Arrangements of heating devices
- Y02P 10/122: by capturing or storing CO2
- Y02P 10/134: by avoiding CO2, e.g. using hydrogen
- C21C: PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21B: MANUFACTURE OF IRON OR STEEL (preliminary treatment of ferrous ores or scrap C22B1/00)
- F27B: FURNACES, KILNS, OVENS OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
- Y02P: CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS

## Abstract

A method and apparatus for reducing iron oxides using microwave heating in a furnace chamber which is sealed against the entrance of air reduces the energy required and produces a low temperature reduction and allows the recovery of combustible synthetic gas as a byproduct of the process. Avoidance of the reduction of sulfur, phosphorus and silica is also insured, as is the need to reduce the silica content of the feed material prior to reducing the ore. A continuous rotary hearth furnace, a rotary kiln, a linear conveyor and vertical shaft furnace chamber configurations are described. A secondary heating zone can also be included to process the reduced iron into iron nuggets or liquid metallic iron.

## Claims

### Claim 1

A method of reducing iron oxide and concurrently generating a combustible syngas comprising charging a feed material including iron oxide mixed with coal which contains moisture and volatiles including primarily methane into a furnace chamber through an inlet port while sealing said furnace chamber against the entrance of air;
dividing said furnace chamber into first and second zones, with said first zone having said inlet port receiving said feed material;
irradiating said feed material with microwave radiation of a sufficient intensity to heat said iron oxide and said coal in said feed material so as to reduce iron oxide in said feed material by reaction of carbon therewith to produce CO2 and CO from said CO2 to continue reduction of iron oxide by reaction of CO therewith, producing direct reduced iron and carbon monoxide;
transporting said direct reduced iron to said second zone in said furnace chamber where said reduced iron oxide in said feed material is heated to a higher temperature to be melted;
reacting carbon dioxide formed by reduction of said iron oxide by carbon monoxide with off gassed volatiles primarily methane from said coal in the presence of further heated direct reduced iron and molten iron as a catalyst in said second zone to form hydrogen and carbon monoxide gas, and reacting any moisture from coal with methane in the presence of said further heated direct reduced iron and molten iron as a catalyst and also reacting any moisture with unreacted carbon in said second zone to thereby also produce hydrogen and carbon monoxide gas to thereby generate said syngas comprised of a mixture of hydrogen and carbon monoxide as a by-product of the production of iron;
and discharging said molten iron from a product discharge port in said second zone and collecting and discharging said combustible syngas from an exhaust port in said second zone of said sealed furnace chamber adjacent said product discharge port to create a substantially concurrent flow through said furnace chamber of said gases with feed material, direct reduced iron and molten iron to promote said reactions producing said syngas.

### Claim 2 (depends on 1)

The method according to claim 1 wherein said microwave irradiation is set to be not intensive enough to reduce any sulfur or phosphorus contained in said feed material.

### Claim 3 (depends on 1)

The method according to claim 1 wherein said furnace chamber is annular and a matching annular hearth is rotated within said furnace chamber to carry feed material around said furnace chamber from said first zone to said second zone.

### Claim 4 (depends on 1)

The method according to claim 1 wherein said furnace chamber extends linearly and a conveyor is disposed along said furnace chamber and said feed material is deposited at one end of said conveyor to carry feed material along said furnace chamber from said first zone to said second zone by said conveyor.

### Claim 5 (depends on 1)

The method according to claim 1 wherein said reduced iron oxide in said feed material is heated sufficiently in said second zone to form iron nuggets.