# US 8,540,173 B2 · Production of fine particles of functional ceramic by using pulsed laser

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- Number: US 8,540,173 B2
- Document ID: US8540173B2
- Status: Granted
- Kind: B2
- Application number: 12/951,557
- Filed: 2010-11-22
- Published: 2011-08-11
- Granted: 2013-09-24
- Earliest claimed: 2010-02-10
- Assignees: Imra America, Inc.
- Applicants: Yuki Ichikawa; Zhengong Hu; Bing Liu; Yong Che
- Inventors: Yuki Ichikawa; Zhengong Hu; Bing Liu; Yong Che
- Web page: https://patentgrep.com/patent/US8540173B2

## CPC

- C09K 11/025: {non-luminescent particle coatings or suspension media}
- C09K 11/08: containing inorganic luminescent materials
- Y10T 428/2982: Particulate matter [e.g., sphere, flake, etc.]
- C09K: MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- Y10T: TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION

## Abstract

A method of forming nanometer sized fine particles of functional ceramic from a bulk functional ceramic, particularly fine particles of phosphorous ceramics from a bulk phosphor material is disclosed. The method relies on irradiation of a bulk phosphorous ceramic in a liquid with an ultrashort-pulsed-laser-fragmentation beam to thereby form nanometer sized particles of the phosphorous ceramic. The method is unique in that the generated particles retain the chemical and crystalline properties of the bulk phosphorous ceramic. The generated solutions are stable colloids from which the particles can be isolated or used as is.

## Claims

### Claim 1

A method of fabricating a solution of fine particles of a multi-element ceramic comprising the steps of:
a) providing a bulk target material of a multi-element ceramic comprising at least three elements with at least a portion of the target material being in contact with at least a portion of a liquid; and
b) irradiating the target material with an ultrashort-pulsed-laser-fragmentation beam having a pulse duration of 500 picoseconds or less and forming fine particles of the multi-element ceramic having an average diameter ranging from 1 to 5000 nanometers, wherein the fine particles retain the chemical composition and crystalline structure of the bulk target material.

### Claim 2 (depends on 1)

The method of claim 1, wherein step a) comprises providing a bulk target material comprising a solidified target formed from micron to millimeter sized powder of the multi-element ceramic by at least one of pressing, sintering, or agglomerating with at least one binder material.

### Claim 3 (depends on 1)

The method of claim 1, wherein step b) comprises forming fine particles having an average diameter of from 1 to 500 nanometers.

### Claim 4 (depends on 1)

The method of claim 1, wherein step b) further comprises using an ultrashort-pulsed-laser-fragmentation beam having a pulse duration of from 10 femtosecond to 20 picoseconds.

### Claim 5 (depends on 1)

The method of claim 1, wherein step b) further comprises using an ultrashort-pulsed-laser-fragmentation beam having a repetition rate of from 10 Hz to 1 GHz.

### Claim 6 (depends on 1)

The method of claim 1, wherein step b) further comprises using an ultrashort-pulsed-laser-fragmentation beam having a repetition rate of from 1 kHz to 100 MHz.

### Claim 7 (depends on 1)

The method of claim 1, wherein step b) further comprises using an ultrashort-pulsed-laser-fragmentation beam having a pulse energy of from 1 nanoJoules to 10 milliJoules.

### Claim 8 (depends on 1)

The method of claim 1, wherein step b) further comprises using an ultrashort-pulsed-laser-fragmentation beam having a center of wavelength that is in the UV, visible, or near infrared region.