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US 8,524,837 B2Granted
Heat-curing powder-lacquer compositions yielding a matte surface after curing of the coating, as well as a simple method for production of same
AssigneeEvonik Degussa GmbH
InventorsWerner Grenda, Emmanouil Spyrou, Thomas Weihrauch, Christoph Lammers, Holger Loesch, Klaus Behrendt
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Abstract
The invention relates to heat-curing powder-lacquer compositions exhibiting a matte surface after curing of the coating, as well as to a simple method for production of the same.
Claims27
A powder-lacquer composition, comprising:
- A) at least one carboxylate-group-comprising polymer having an acid number of 5 to 250 mg KOH/g and a glass transition temperature Tg higher than 40° C.;
- and
- B) at least one β-hydroxyalkylamide having two or three or four β-hydroxyalkylamide groups per molecule of formula (I)
- wherein
- R1 and R2, independently of one another denote the same or different radicals, selected from the group consisting of an alkyl radical, a cycloalkyl radical, an aryl radical, an aralkyl radical, and an alkenyl radical, having 1-24 carbon atoms, optionally comprising at least one member selected from the group consisting of a heteroatom and a functional group,
- or R1 is hydrogen,
- or R2 is
- and A is at least one member selected from the group consisting of
- wherein R3 independently of one another denote the same or different radicals, selected from the group consisting of hydrogen, an alkyl radical, a cycloalkyl radical, an aryl radical, an aralkyl radical, and an alkenyl radical, having 1-24 carbon atoms, optionally comprising at least one member selected from the group consisting of a heteroatom and a functional group, and wherein two or more R3 substituents are optionally linked to one another to form rings;
- wherein the β-hydroxyalkylamide exists in solid form below 150° C.;
- C) optionally, at least one member selected from the group consisting of a processing aid and an additive;
- wherein a ratio of β-hydroxyalkylamide groups to carboxylate groups ranges between 0.5:1 and 1.5:1,
- and wherein component (B) has two endothermic peaks according to DSC analysis (differential scanning calorimetry).
10 more elements
Dependencies are inferred from the claim text.