Liquid sample analyzing apparatus and liquid sample introducing apparatus

A liquid sample analyzing apparatus having a mobile phase flow passage, comprising:

• a sample storage loop;
• a pump means for discharging a liquid sample from said sample storage loop;
• a needle for sucking and discharging a sample;
• a first flow passage exchanging means having a sample injection port into which said needle is inserted, said first flow passage exchanging means exchanging whether separating said sample storage loop from said mobile phase flow passage and connecting said sample storage loop to said sample injection port or separating said sample storage loop from said sample injection port and connecting said sample storage loop to said mobile phase flow passage;
• a syringe means for accounting a sample and to suck a sample from a sample container into the needle and to discharge a sample into said sample storage loop from the needle;
• a washing tank into which said needle is inserted;
• a washing pump for feeding a washing solution;
• a second flow passage exchanging means for exchanging a connection and a separation of said needle with said syringe means, a connection and a separation of said needle and said washing pump, and a connection and a separation of said washing tank and said washing pump;
• a needle moving mechanism for moving said needle between an inner of said sample container, said sample injection port, and said washing tank;
• a detection means for analyzing a liquid sample discharged from said sample storage loop;
• a control unit for controlling operations of said first flow passage exchanging means, said syringe means, said washing pump, said second flow passage exchanging means, said pump means and said needle moving mechanism,
• wherein said second flow passage exchanging means connects said washing tank to said washing pump in condition that said needle and said syringe means are connected with each other, and
• said washing pump feeds a washing solution to the inner of said needle and said washing tank through said second flow passage exchanging means.

A method for introducing a sample into a liquid sample analyzing apparatus having a mobile phase flow passage, comprising the steps of:

• a step for sucking a liquid sample into a needle which sucks and discharges a liquid sample while accounting a liquid sample by means of a syringe means;
• a step for connecting said needle to a sample injection port of a first flow passage exchanging means, and supplying a liquid sample sucked into said needle to a sample storage loop of said first flow passage exchanging means while accounting a liquid sample sucked in said needle by using said syringe means;
• a step for separating said needle from said sample injection port of said first flow passage exchanging means, and for supplying a liquid sample stored in said sample storage loop to said mobile phase flow passage;
• a step for connecting a washing tank with a washing pump, and said syringe means with said needle by a second flow passage exchanging means exchanging a connection and a separation of said needle with said syringe means, a connection and a separation of said needle and said washing pump, and a connection and a separation of said washing tank and said washing pump, and for feeding a washing solution by said washing pump to said washing tank to wash an external wall of a needle in condition that said external wall of said needle is inserted into said washing tank;
• and
• a step for separating said needle from said syringe means by said second flow passage exchanging means to connect said needle to said washing pump, and for supplying a washing solution into said needle by said washing pump, and for washing an inner wall of said needle.