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US 8,507,736 B2Granted
Gas phase process for monoalcohol production from glycerol
AssigneeBioFuel-Solution i Malmo AB
InventorsChristian Hulteberg, Jan Brandin, Richard R. Woods, Brook Porter
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Abstract
A method of producing short chain alcohols from glycerol generated as a byproduct of biodiesel production is provided.
Claims26
A method for converting glycerol to monohydric alcohol, the method comprising:
- reacting a gaseous mixture comprising glycerol, water and hydrogen in a first reaction bed comprising a heterogeneous catalyst system comprising a dehydration catalyst and a hydrogenation catalyst, whereby a first reacted mixture is produced, the first reaction mixture comprising propionaldehyde;
- separating at least a portion of the first reacted mixture into a more volatile fraction and a less volatile fraction in a first condenser;
- reacting a mixture of hydrogen and at least a portion of the more volatile fraction from the first reacted mixture in a second reactor bed comprising a hydrogenation catalyst, whereby a second reacted mixture comprising a monohydric alcohol is produced;
- separating at least a portion of the second reacted mixture into a less volatile fraction comprising a monohydric alcohol and a more volatile fraction in a second condenser.
1 more element
Dependencies are inferred from the claim text.