Method for producing hydrocarbon oxysilicon compounds
AssigneeWacker Chemie AG
InventorsMichael Stepp, Markus Merget
Life of this patent
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Abstract
The invention relates to a method for producing silicon compounds (A) having hydrocarbon oxy-groups that have at least one unit of the general formula (1) HmSi(OR)n(OR′)oR″pX4-m-n-o-p (1) by conversion of silicon compounds (B) having at least one unit of the general formula (2) Hm+nSi(OR′)oR″pX4-m-n-o-p (2), having an alcohol of the general formula (3) ROH (3) in the presence of a catalyst (K) that is on a carrier material bonded metal selected from Ni, Pd, Pt, wherein per mol formed group OR, at maximum 1 liter of solvent is used and wherein R, R′, R″, X, m, n, o and p have the meanings listed in claim 1.
Claims19
A process for preparing silicon compound products which have hydrocarbonoxy groups and have at least one unit of the general formula (1)
- HmSi(OR)n(OR′)oR″pX4-m-n-o-p (1)
- said method comprising reacting silicon compound reactants which have at least one unit of the general formula (2)
- Hm+nSi(OR′)oR″pX4-m-n-o-p (2)
- with an alcohol of the general formula (3)
- ROH (3)
- in the presence of a catalyst which is a metal selected from the group consisting of Ni, Pd and Pt bound to a support material, where not more than one liter of solvent is used per mole of OR group formed and
- R is a monovalent hydrocarbon radical which has from 1 to 18 carbon atoms and is optionally substituted by OH groups, halogen atoms, silyl groups, siloxy groups, —CN, —COOR1, —OCOOR2, —CONR3R4, —OCONR5R6, —NR7CONR8R9, —SO2—R10, —OSO2—R11, —OP(OR12)(OR13), where a carbon chain thereof is optionally interrupted by nonadjacent —(CO)—, —O—, —S— or —NR14— groups;
- R′, R″ are each a monovalent hydrocarbon radical which has from 1 to 18 carbon atoms and is optionally substituted by halogen atoms, silyl groups, siloxy groups, —CN, —COOR1, —OCOOR2, —CONR3R4, —OCONR5R6, —NR7CONR8R9, —SO2—R10, OSO2—R11, —OP(OR12)(OR13), where a carbon chain thereof is optionally interrupted by nonadjacent —(CO)—, —O—, —S— or —NR14— groups;
- R1 to R14 are each a monovalent hydrocarbon radical which has from 1 to 18 carbon atoms and is optionally substituted by halogen atoms,
- X is a chemical bond via which radicals containing silicon atoms are bound,
- m is 0, 1, 2 or 3,
- n is 1, 2 or 3,
- m+n is 1, 2 or 3,
- o is 0, 1, 2 or 3,
- p is 0, 1, 2 or 3 and
- m+n+o+p is 1, 2, 3 or 4.
Dependencies are inferred from the claim text.