Stable sub-micron titania sols
AssigneeCristal USA Inc.
InventorDavid M. Chapman
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Abstract
The present invention is directed to compositions and processes for the production of stable, alkaline, high solids, low viscosity, low surface tension, low flammability, sub-micron titania sols that have minimal offensive odor and methods of their use. Compositions of the present invention include, for example, mixtures of strong and weak organic bases used as dispersants to stabilize the titania sols. The dispersant mixtures have been found to result in relatively high titania solids content, low surface tension, low viscosity suspensions that are low in flammability. Sols produced according to the present invention can be used, for example, in catalytic applications such as catalyst supports for diesel emission control, or in pollutant photocatalyst applications in which it is desirable to have the titania in sol form.
Claims8
A method of producing an aqueous ultrafine titania sol having (1) a pH >10, (2) a solids component having at least 50% by weight of anatase crystal form of TiO2 particles and less than 50% by weight of at least one inorganic oxide other than TiO2, and (3) an aqueous component comprising a mixture of a weak base having a pKa <10.5 and a strong base having a pKa >10.5, wherein the anatase crystal form of TiO2 particles are present in the aqueous titania sol at a mass fraction >0.25 and/or a volume fraction >0.25, comprising the step of processing the aqueous ultrafine titania sol via media milling until the anatase crystal form of TiO2 particles therein have a particle size <1 μm.
Dependencies are inferred from the claim text.