N-alkoxylated 2,3-anthraquinonedicarboximides for polymer coloration, preparation and use

A compound of formula (I)

• where
• T represents, hydroxyl, amino, mono-(C1-C15)-alkylamino, bis-(C1-C15)-alkylamino, aryl, aryloxy, , monohydroxy-(C1-C15)-alkyl, polyhydroxy-(C1-C15)-alkyl or (C1-C15)-alkyl-aryloxy
• or represents a group of formula (1)
• or represents a group of formula (2)
• or represents a group of formula (3)
• Q1 to Q4 each represents a group of formula (4)
• where
• r represents a rational number from 0.1 to 200 and has identical or different meanings within any one molecule of formula (I);
• R25 and R26 each dependently represent hydrogen, (C1-C15)-alkyl, singly or multiply oxygen-interrupted (C1-C15)-alkyl, aryl, aryloxy, (C1-C15)-alkoxy, monohydroxy-(C1-C15)-alkyl or polyhydroxy-(C1-C15)alkyl;
• and where R25 and R26 have identical or different meanings within any one molecule of formula (I);
• and
• where when R25 and R26 have different meanings within any one molecule of formula (I) these different meanings are randomly distributed or regions of respectively identical meanings follow each other;
• and wherein the groups T, A and B are bonded to the bond * or to the bond **;
• R1 to R24 each independently represent hydrogen;
• (C1-C15)-alkyl;
• trifluoromethyl;
• cyclo-(C3-C8)-alkyl;
• aryl;
• heteroaryl;
• heterocycloalkyl;
• halogen;
• cyano;
• nitro;
• hydroxyl;
• (C1-C15)-alkoxy;
• aryloxy;
• (C2-C15)-acyl;
• arylcarbonyl, (C2-C15)-acyloxy;
• arylcarbonyloxy;
• (C2-C15)-acylamino;
• (C1-C15)-alkylsulfonylamino;
• arylsulfonylamino;
• arylcarbonylamino;
• carbamoyl;
• N-monocyclo-(C3-C8)-alkyl-carbamoyl;
• N-mono-(C1-C15)-alkyl-carbamoyl;
• N,N-dicyclo-(C3-C8)-alkyl-carbamoyl;
• N,N-di-(C1-C15)-alkyl-carbamoyl;
• N-monoaryl-carbamoyl;
• N,N-diaryl-carbamoyl;
• N-monocyclo-(C3-C8)-alkyl-N-monoarylcarbamoyl;
• N-mono-(C1-C15)-alkyl-N-monoarylcarbamoyl;
• (C1-C15)-alkoxycarbonyl;
• aryloxycarbonyl;
• amino;
• monocyclo-(C3-C8)-alkyl-amino;
• mono-(C1-C15)-alkyl-amino;
• di(cyclo)-(C3-C8)-alkyl-amino;
• di-(C1-C15)-alkyl-amino;
• monoaryl-amino;
• diaryl-amino;
• monocyclo-(C3-C8)-alkylmonoarylamino;
• mono-(C1-C15)-alkylmonoaryl-amino;
• aminothiocarbonylamino;
• aminocarbonylamino;
• sulfamoyl;
• N-monocyclo-(C3-C8)-alkyl-sulfamoyl;
• N-mono-(C1-C15)-alkyl-sulfamoyl;
• N,N-dicyclo-(C3-C8)-alkyl-sulfamoyl;
• N,N-di-(C1-C15)-alkyl-sulfamoyl;
• N-monoaryl-sulfamoyl;
• N,N-diaryl-sulfamoyl;
• N-monocyclo-(C3-C8)-alkyl-N-monoarylsulfamoyl;
• N-mono-(C1-C15)-alkyl-N-monoarylsulfamoyl;
• aminosulfonylamino;
• (C1-C15)-alkylthio;
• arylthio;
• (C1-C15)-alkylsulfonyl or arylsulfonyl;
• or each independently represent (C1-C15)-alkyl, N-mono-(C1-C15)-alkylamino, N,N-di-(C1-C15)-alkylamino, N—(C1-C15)-alkyl-N-cyclo-(C3-C8)-alkylamino, N—(C1-C15)-alkyl-N-arylamino, (C1-C15)-alkoxy, (C1-C15)-alkylthio, (C2-C15)-acyl or (C1-C15)-alkylsulfonyl which are each substituted by one or more substituents selected from the group consisting of hydroxyl, (C3-C8)-cycloalkyl, heteroaryl, heterocyclo-(C3-C8)-alkyl, aryl, aryloxy, (C1-C15)-alkoxy, (C1-C15)-alkylthio, arylthio, poly(oxy-(C1-C15)-alkylene)s, halogen, cyano, (C1-C15)-alkoxycarbonyl, (C1-C15)-alkoxythiocarbonyl, (C2-C15)-acyloxy, carbamoyl, sulfamoyl, nitro, amino, (C2-C15)-acylamino, arylcarbonylamino, (C1-C15)-alkylsulfonylamino, arylsulfonylamino, aminocarbonylamino, aminothiocarbonylamino, N-mono-(C1-C15)-alkylamino, N-mono-(hydroxy-(C1-C15)-alkyl)amino, N,N-bis-(hydroxy-(C1-C15)-alkyl)amino, N-mono-(C1-C15)-alkoxy-(C1-C15)-alkyl)amino, N,N-bis-(C1-C15)-alkoxy-(C1-C15)-alkyl)amino, N-mono-(C1-C15)-alkoxy-(C1-C15)-alkyl)amino, N-mono-(C1-C15)-alkylthio-(C1-C15)-alkyl)amino, N-bis-(C1-C15)-alkylthio-(C1-C15)-alkyl)amino, N-monocyclo-(C3-C8)-alkylamino, N-monoaryl-amino, N,N-di-(C1-C15)-alkyl-amino, N,N-dicyclo-(C3-C8)-alkylamino, N,N-diaryl-amino, N—(C1-C15)-alkyl-N-aryl-amino, N-cyclo-(C3-C8)-alkyl-N-aryl-amino or aminosulfonylamino;
• or each independently represent aryl, monoaryl-amino;
• diaryl-amino, aryloxy, arylthio, arylcarbonyl, arylcarbonyloxy;
• arylsulfonylamino;
• arylcarbonylamino, N-monoaryl-carbamoyl;
• N,N-diaryl-carbamoyl, N-monocyclo-(C3-C8)-alkyl-N-monoarylcarbamoyl;
• N-mono-(C1-C15)-alkyl-N-monoarylcarbamoyl;
• mono cyclo-(C3-C8)-alkylmono arylamino;
• mono-(C1-C15)-alkylmonoaryl-amino;
• N-monoaryl-sulfamoyl;
• N,N-diaryl-sulfamoyl;
• N-monocyclo-(C3-C8)-alkyl-N-monoarylsulfamoyl;
• N-mono-(C1-C15)-alkyl-N-monoarylsulfamoyl or arylsulfonyl, wherein the aryl radical is substituted by one or more substituents selected from the group consisting of hydroxyl, (C1-C15)-alkyl, (C3-C8)-cycloalkyl, heteroaryl, heterocyclo-(C3-C8)-alkyl, (C1-C15)-alkoxy, (C1-C15)-alkylthio, poly(oxy-(C1-C15)-alkylene)s, halogen, cyano, (C1-C15)-alkoxycarbonyl, (C1-C15)-alkoxythiocarbonyl, (C2-C15)-acyloxy, carbamoyl, N-monocyclo-(C3-C8)-alkyl-carbamoyl, N-mono-(C1-C15)-alkyl-carbamoyl, N,N-dicyclo-(C3-C8)-alkyl-carbamoyl, N,N-di-(C1-C15)-alkyl-carbamoyl, N-monoaryl-carbamoyl, N,N-diaryl-carbamoyl, N-monocyclo-(C3-C8)-alkyl-N-monoarylcarbamoyl, N-mono-(C1-C15)-alkyl-N-monoarylcarbamoyl, sulfamoyl, N-monocyclo-(C3-C8)-alkyl-sulfamoyl, N-mono-(C1-C15)-alkyl-sulfamoyl, N-mono-(hydroxy-(C1-C15)-alkyl)sulfamoyl, N,N-dicyclo-(C3-C8)-alkyl-sulfamoyl, N,N-di-(C1-C15)-alkyl-sulfamoyl, N-monoaryl-sulfamoyl, N,N-diaryl-sulfamoyl, N-monocyclo-(C3-C8)-alkyl-N-monoarylsulfamoyl, N-mono-(C1-C15)-alkyl-N-monoarylsulfamoyl, nitro, amino, (C2-C15)-acylamino, arylcarbonylamino, (C1-C15)-alkylsulfonylamino, arylsulfonylamino, aminocarbonylamino, aminothiocarbonylamino, N-mono-(C1-C15)-alkylamino, N-mono-(hydroxy-(C1-C15)-alkyl)amino, N,N-bis-(hydroxy-(C1-C15)-alkyl)amino, N-mono((C1-C15)-alkoxy-(C1-C15)-alkyl)amino, N,N-bis-((C1-C15)-alkoxy-(C1-C15)-alkyl)amino, N-mono-((C1-C15)-alkoxy-(C1-C15)-alkyl)amino, N-mono-((C1-C15)-alkylthio-(C1-C15)-alkyl)amino, N-bis-((C1-C15)-alkylthio-(C1-C15)-alkyl)amino, N-monocyclo-(C3-C8)-alkylamino, N-monoaryl-amino, N,N-di-(C1-C15)-alkyl-amino, N,N-dicyclo-(C3-C8)-alkylamino, N,N-diaryl-amino, N—(C1-C15)-alkyl-N-aryl-amino, N-cyclo-(C3-C8)-alkyl-N-aryl-amino or aminosulfonylamino;
• R30 to R33 each independently represent hydrogen, (C1-C15)-alkyl, singly or multiply oxygen-interrupted (C1-C15)-alkyl, aryl, aryl-(C1-C15)-alkyl, (C1-C15)-alkyl-aryl, aryloxy, (C1-C15)-alkoxy, monohydroxy-(C1-C15)-alkyl or polyhydroxy-(C1-C15)-alkyl and have identical or different meanings within any one molecule of formula (I);
• x represents a number from 1 to 30;
• y, z and t each independently represent a number from 0 to 30;
• A represents a group of formula (5)
• where
• a, b and c each independently represent a number from 0 to 15;
• R27 represents hydrogen, (C1-C15)-alkyl, singly or multiply oxygen-interrupted (C1-C15)-alkyl, aryloxy, (C1-C15)-alkoxy, monohydroxy-(C1-C15)alkyl or polyhydroxy-(C1-C15)-alkyl;
• and
• B represents a group of formula (6)
• where
• a, b, c and d each independently represent a number from 0 to 15.