Detergent compositions

A shading composition for fabric treatment comprising:

• (a) a phthalocyanine compound of formula (1a)
• in which
• PC is the phthalocyanine ring system,
• Me is Zn;
• Ca;
• Mg;
• Na;
• K;
• Al—Z1;
• Si(IV)-(Z1)2;
• Ti(IV)-(Z1)2;
• Ge(IV)-(Z1)2;
• Ga(III)-Z1;
• Zr(IV)-(Z1)2;
• In(III)-Z1 or Sn(IV)-(Z1)2;
• Z1 is an alkanolate ion;
• a hydroxyl ion;
• R0COO−;
• ClO4−;
• BF4−;
• PF6−;
• R0SO3−;
• SO42−;
• NO3;
• F;
• Cl;
• Br;
• I;
• citrate ion;
• tartrate ion or oxalate ion, wherein R0 is hydrogen;
• or unsubstituted C1-C18 alkyl;
• r is 0;
• 1;
• 2;
• 3 or 4;
• r′ is 1;
• 2;
• 3 or 4;
• each Q2 is independently of each other —SO3−M+ or a group —(CH2)m—COO−M+;
• wherein M+ is H+, an alkali metal ion or the ammonium ion and m is 0 or a number from 1 to 12;
• each Q′ is independently from each other a moiety of formula -L-D wherein
• D is a radical of a mono-azo dyestuff, wherein each D is independently selected from a dyestuff radical of formulae (10), (11), (12), (13) or (14):
• wherein # marks the bond to the bridging group L;
• and L is a group:
• wherein
• R20 is hydrogen, C1-C8 alkyl, C1-C8 alkoxy or halogen;
• R21 is independently D, hydrogen, OH, Cl or F, with the proviso that at least one is D;
• R100 is C1-C8 alkylene
• * is the point of attachment of PC;
• # is the point of attachment to D;
• and
• (b) a fabric treatment adjunct material.