Copolymer, resin composition, spacer for display panel, planarization film, thermosetting protective film, microlens, and process for producing copolymer
AssigneeTokyo Ohka Kogyo Co., Ltd.
InventorMasayuki Endo
Life of this patent
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Abstract
Without the use of a third monomer, no copolymer practicable as a base polymer for a radiation-sensitive resin composition has been obtained by copolymerizing two ingredients, i.e., a carboxylated monomer and an epoxidized monomer. A carboxylated monomer is reacted with a specific nonpolymerizable compound, and this reaction mixture is then copolymerized with an epoxidized monomer. A radiation-sensitive resin composition and a thermosetting resin composition each containing the resultant copolymer have satisfactory storage stability and are useful as a spacer for liquid-crystal display panels, etc., a planarization film for TFT elements, and a protective film for color filters.
Claims8
A resin composition, comprising a copolymer [A] and an organic solvent [B], the copolymer [A] comprising an epoxy group and a carboxyl group, and having a constitutional component derived from (a1) and a constitutional component derived from (a2) below:
- (a1) a reaction mixture between at least one of an ethylenically unsaturated carboxylic acid and an ethylenically unsaturated carboxylic acid anhydride and at least one reactive compound selected from the group consisting of the compounds represented by general formulae (I), (II) and (III) below,
- R1—O—R3—O—R2 (I)
- wherein, R1 and R2 each independently represent an alkyl group having 1 to 4 carbon atoms, and R3 represents a linear hydrocarbon group having 2 to 4 carbon atoms which does not contain an oxygen atom, or a linear or branched hydrocarbon group having 2 to 4 carbon atoms which contains an oxygen atom,
- wherein, R4 and R5 each independently represent an alkyl group having 1 to 4 carbon atoms,
- wherein, R6 and R7 each independently represent an alkyl group having 1 to 4 carbon atoms, and R8 represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms;
- and
- (a2) at least one epoxidized ethylenically-unsaturated compound selected from the group consisting of glycidyl acrylate, 2-methyl glycidyl acrylate, 3,4-epoxy butyl acrylate, 6,7-epoxy heptyl acrylate, glycidyl methacrylate, 2-methyl glycidyl methacrylate, 3,4-epoxy butyl methacrylate, 6,7-epoxy heptyl methacrylate, α-glycidyl ethyl acrylate, α-n-glycidyl propyl acrylate, α-n-butyl acryl glycidyl, α-ethyl acrylate 6,7-epoxyheptyl, o-vinyl benzyl glycidyl ether, m-vinyl benzyl glycidyl ether and p-vinyl benzyl glycidyl ether.
Dependencies are inferred from the claim text.