Method and system for the production of potassium sulfate from potassium chloride
AssigneeNichromet Extraction Inc.
InventorsJean-Marc Lalancette, David Lemieux, Bertrand Dubreuil
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Abstract
A method and a system for the production of potassium sulfate. The method comprises reacting a chloride of potassium with a magnesium sulfate in an aqueous alcoholic solution, with recycling of magnesium sulfate and production of hydrochloric acid, where the recycling of magnesium is done by a reaction of sulfuric acid on resulting magnesium chloride with corresponding production of magnesium sulfate and hydrochloric acid.
Claims9
A method for the production of potassium sulfate, comprising reacting a chloride of potassium with a magnesium sulfate in an aqueous alcoholic solution, with recycling of magnesium sulfate and production of hydrochloric acid, wherein the recycling of magnesium is done by a reaction of sulfuric acid on resulting magnesium chloride with corresponding production of magnesium sulfate and hydrochloric acid.
A method for the production of potassium sulfate comprising reacting a source of water soluble potassium with a magnesium sulfate-containing substance in presence of an aqueous alcoholic solution, wherein said reacting the source of water soluble potassium with the magnesium sulfate-containing substance in presence of the aqueous alcoholic solution is performed at a temperature in a range comprised between 50 and 65° C.
A system for the production of potassium sulfate, comprising:
- a first reactor for dissolving a water soluble potassium in water into a first solution;
- a second reactor for dissolving magnesium sulfate hydrate in water and adding methanol into a second solution;
- a third reactor, adapted to receive the first and the second solutions, mixed then under stirring and cool them down into a slurry;
- a filter collecting and filtering the slurry from the third reactor;
- delivering, after rinsing of the solid part with methanol, chloride-free potassium sulfate, and a combined filtrate and rinsings;
- a column receiving and distilling the combined filtrate and rinsings, delivering methanol back to the second reactor and to the filter and a concentrated solution of magnesium chloride;
- a fourth reactor, adapted to receive the concentrated solution of magnesium chloride, which crystallizes upon cooling, and to treat the concentrate with sulfuric acid, delivering hydrochloric acid and a residual mass;
- a collector, adapted to absorb the hydrochloric acid delivered form from the fourth reactor;
- and
- a fifth reactor, adapted to collect and crystallise the residual mass from the fourth reactor, for recycling to the second reactor as magnesium sulfate heptahydrate.
Dependencies are inferred from the claim text.