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US 8,409,368 B2Granted
Manufacturing method of grain-oriented magnetic steel sheet
AssigneeNippon Steel & Sumitomo Metal Corporation
InventorsYoshiyuki Ushigami, Norikazu Fujii
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Abstract
A nitriding treatment (Step S6) in which an N content of a decarburization-annealed steel strip is increased is performed between start of a decarburization annealing (Step S4) and occurrence of secondary recrystallization in a finish annealing (Step S5). In hot rolling (Step S1), a silicon steel material is held in a temperature range between 1000° C. and 800° C. for 300 seconds or longer, and then finish rolling is performed.
Claims25
A manufacturing method of a grain-oriented electrical steel sheet, comprising:
- hot rolling a silicon steel material so as to obtain a hot-rolled steel strip, the silicon steel material containing Si:
- 0.8 mass % to 7 mass %, acid-soluble Al:
- 0.01 mass % to 0.065 mass %, N:
- 0.004 mass % to 0.012 mass %, Mn:
- 0.05 mass % to 1 mass %, Ti:
- 0.004 mass % or less and B:
- 0.0005 mass % to 0.0080 mass %, the silicon steel material further containing at least one element selected from a group consisting of S and Se being 0.003 mass % to 0.015 mass % in total amount, a C content being 0.085 mass % or less, and a balance being composed of Fe and inevitable impurities;
- annealing the hot-rolled steel strip so as to obtain an annealed steel strip;
- cold rolling the annealed steel strip one time or more so as to obtain a cold-rolled steel strip;
- decarburization annealing the cold-rolled steel strip so as to obtain a decarburized-annealed steel strip in which primary recrystallization is caused;
- coating an annealing separating agent containing MgO as its main component on the decarburized-annealed steel strip;
- and
- causing secondary recrystallization by finish annealing the coated decarburized-annealed steel strip, wherein
- the method further comprises performing a nitriding treatment in which an N content of the decarburized-annealed steel strip is increased between start of the decarburization annealing and occurrence of the secondary recrystallization in the finish annealing,
- wherein the hot rolling comprises:
- holding the silicon steel material in a temperature range from 1000° C. to 800° C. for 300 seconds or longer;
- and
- then performing finish rolling.
15 more elements
Dependencies are inferred from the claim text.