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US 8,383,848 B2Granted
Transition metal compound and catalyst for olefin polymerization
AssigneeSumitomo Chemical Company, Limited
InventorsHidenori Hanaoka, Masato Takano, Naoko Ochi, Kazuo Takaoki, Kazuyuki Ito, Masayuki Hasegawa
Life of this patent
Estimating the term…
Abstract
A transition metal compound represented by the formula (1-1) or the formula (1-2) (M is a transition metal atom) and a process for producing a catalyst for olefin polymerization comprising a step of bringing the transition metal compound into contact with a co-catalytic component for activation.
Claims10
A transition metal compound represented by the formula (1-2):
- wherein M represents a transition metal atom of the Group 3, 4, 5, Group lanthanide or Group actinide of the periodic table,
- (i) R1 and R2 are the same as, or different from each other, and represent an alkyl group having 1 to 20 carbon atoms and optionally having a halogen atom as a substituent,
- a cycloalkyl group having 3 to 10 carbon atoms and optionally having a halogen atom as a substituent,
- an alkenyl group having 2 to 20 carbon atoms and optionally having a halogen atom as a substituent,
- an alkynyl group having 2 to 20 carbon atoms and optionally having a halogen atom as a substituent,
- an aralkyl group having 7 to 20 carbon atoms and optionally having a halogen atom as a substituent, or
- an aryl group having 6 to 20 carbon atoms and optionally having a halogen atom as a substituent,
- (ii) R3 and R4 are the same as, or different from each other, and represent a hydrogen atom,
- an alkyl group having 1 to 20 carbon atoms and optionally having a halogen atom as a substituent,
- a cycloalkyl group having 3 to 10 carbon atoms and optionally having a halogen atom as a substituent,
- an alkenyl group having 2 to 20 carbon atoms and optionally having a halogen atom as a substituent,
- an alkynyl group having 2 to 20 carbon atoms and optionally having a halogen atom as a substituent,
- an aralkyl group having 7 to 20 carbon atoms and optionally having a halogen atom as a substituent, or
- an aryl group having 6 to 20 carbon atoms and optionally having a halogen atom as a substituent,
- (iii) R5 to R8 are the same as, or different from one another, and represent a hydrogen atom,
- an alkyl group having 1 to 20 carbon atoms and optionally having a halogen atom as a substituent,
- a cycloalkyl group having 3 to 10 carbon atoms and optionally having a halogen atom as a substituent,
- an alkenyl group having 2 to 20 carbon atoms and optionally having a halogen atom as a substituent,
- an alkynyl group having 2 to 20 carbon atoms and optionally having a halogen atom as a substituent,
- an aralkyl group having 7 to 20 carbon atoms and optionally having a halogen atom as a substituent,
- an aryl group having 6 to 20 carbon atoms and optionally having a halogen atom as a substituent,
- an alkoxy group having 1 to 20 carbon atoms and optionally having a halogen atom as a substituent,
- an aralkyloxy group having 7 to 20 carbon atoms and optionally having a halogen atom as a substituent,
- an aryloxy group having 6 to 20 carbon atoms and optionally having a halogen atom as a substituent,
- a silyl group optionally having, as a substituent, a hydrocarbyl group or a halogenated hydrocarbyl group having 1 to 20 carbon atoms,
- an amino group optionally having, as a substituent, a hydrocarbyl group or a halogenated hydrocarbyl group having 1 to 20 carbon atoms, or
- a heterocyclic compound residue,
- (iv) R1 and R3, R2 and R4, R5 and R6, R5 and R7, or R7 and R8 may be taken together with each other to form a ring, wherein the ring may have a substituent;
- A2 represents a —[Z(R11)(R12)]n-group, wherein Z represents a silicon atom, a germanium atom, a tin atom or a carbon atom, R11 and R12 are the same as, or different from each other, and represent a hydrogen atom,
- an alkyl group having 1 to 20 carbon atoms and optionally having a halogen atom as a substituent,
- a cycloalkyl group having 3 to 10 carbon atoms and optionally having a halogen atom as a substituent,
- an aryl group having 6 to 20 carbon atoms and optionally having a halogen atom as a substituent, or
- a silyl group optionally having, as a substituent, a hydrocarbyl group or a halogenated hydrocarbyl group having 1 to 20 carbon atoms, and
- n represents 1, 2, 3 or 4, and when plural Zs, R11s or R12s exist, they may be the same as, or different from one another,
- X represents a hydrogen atom, a fluorine atom, a chlorine atom, a bromine atom, an iodine atom,
- an alkyl group having 1 to 20 carbon atoms and optionally having a halogen atom as a substituent,
- a cycloalkyl group having 3 to 10 carbon atoms and optionally having a halogen atom as a substituent,
- an aralkyl group having 7 to 20 carbon atoms and optionally having a halogen atom as a substituent,
- an aryl group having 6 to 20 carbon atoms and optionally having a halogen atom as a substituent,
- an alkoxy group having 1 to 20 carbon atoms and optionally having a halogen atom as a substituent,
- an aralkyloxy group having 7 to 20 carbon atoms and optionally having a halogen atom as a substituent,
- an aryloxy group having 6 to 20 carbon atoms and optionally having a halogen atom as a substituent,
- a silyl group optionally having, as a substituent, a hydrocarbyl group or a halogenated hydrocarbyl group having 1 to 20 carbon atoms,
- an amino group optionally having, as a substituent, a hydrocarbyl group or a halogenated hydrocarbyl group having 1 to 20 carbon atoms,
- a thiolate group optionally having, as a substituent, a hydrocarbyl group or a halogenated hydrocarbyl group having 1 to 20 carbon atoms, or
- a carboxylate group optionally having, as a substituent, a hydrocarbyl group or a halogenated hydrocarbyl group having 1 to 20 carbon atoms, and when plural Xs exist, they are the same as, or different from each other, and adjacent Xs may be taken together with each other to form a ring;
- k represents 1, 2 or 3;
- L represents a neutral Lewis base, and when plural Ls exist, plural Ls are the same as, or different from each other;
- m represents 0, 1, 2, 3 or 4;
- the sum of k and m is 2, 3 or 4.
47 more elements
Dependencies are inferred from the claim text.