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US 8,378,153 B2Granted
Process for the production of alcohol from a carbonaceous feedstock
AssigneeBp P.L.C.
InventorsBerian John Daniel, Jon Michael Stewart Deeley, Benjamin Patrick Gracey, Cong Rong Li
Life of this patent
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Abstract
The present invention relates to an improved process for the production of ethanol from a carbonaceous feedstock; wherein the carbonaceous feedstock is first converted to synthesis gas which is then converted to ethanoic acid, which is then esterified and which is then hydrogenated to produce ethanol.
Claims10
A process for the production of ethanol from ethanoic acid and H2, characterised by the following steps:
- 1) introducing ethanoic acid, together with methanol and/or ethanol into an esterification reactor containing an esterification catalyst to produce methyl ethanoate and/or ethyl ethanoate,
- 2) introducing methyl ethanoate and/or ethyl ethanoate from step 1, together with H2 and water, into a hydrogenation unit comprising a hydrogenation catalyst to produce a stream comprising ethanol, unreacted methyl ethanoate and/or ethyl ethanoate and optionally methanol,
- 3) separating the resulting stream, from step 2, into unreacted methyl ethanoate and/or ethyl ethanoate and ethanol and optionally methanol,
- 4) optionally reintroducing methyl ethanoate and/or ethyl ethanoate, from step 3, into the esterification reactor of step 1,
- 5) using at least a part of the methanol and/or the ethanol of step 3, as the methanol and/or ethanol feed of the esterification reactor of step 1, and
- 6) recovering ethanol, from step 3.
3 more elements
Dependencies are inferred from the claim text.