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US 8,343,381 B1Granted
Hole transport composition
AssigneeE. I. Du Pont de Nemours and Company
InventorReid John Chesterfield
Life of this patent
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Abstract
There is provided a hole transport composition having (i) a first hole transport polymer having crosslinkable groups, and (ii) a second hole transport polymer having substantially no crosslinkable groups. There is also provided a crosslinked hole transport layer and an electronic device containing the crosslinked hole transport layer.
Claims5
A hole transport composition comprising (i) a first hole transport polymer made from at least one first monomer selected from A1, A2, and A3
- where:
- R is the same or different at each occurrence and is selected from the group consisting of H, D, alkyl, fluoroalkyl, aryl, fluoroaryl, alkoxy, aryloxy, NR″2, R′,
- R′ is a crosslinkable group;
- R″ is independently selected from the group consisting of H, alkyl, fluoroalkyl, aryl, fluoroaryl, and R′;
- X can be the same or different at each occurrence and is a leaving group;
- Z is C, Si, or N;
- Q is the same or different at each occurrence and is (ZR″n)b;
- a is an integer from 0 to 5;
- b is an integer from 0 to 20;
- c is an integer from 0 to 4;
- q is an integer from 0 to 7;
- and
- n is an integer from 1 to 2;
- wherein there is at least one crosslinkable group;
- and (ii) a second hole transport polymer having substantially no crosslinkable groups, wherein said second hole transport polymer is selected from the group consisting of a polymer having Formula (IX), and a polymer having Formula X:
- wherein:
- Ar1 is the same or different at each occurrence and is selected from the group consisting of phenylene and naphthylene;
- Ar2 is the same or different at each occurrence and is an aryl group;
- M is the same or different at each occurrence and is a conjugated moiety;
- T1 and T2 are independently the same or different at each occurrence and are conjugated moieties which are connected in a non-planar configuration;
- d is an integer from 1 to 6;
- e, f, and g are mole fractions such that e+f+g=1.0, with the proviso that f is not zero, and at least one of e and g is not zero, and when e is zero, M comprises at least two triarylamine units;
- and
- m is an integer greater than 5.
21 more elements
Dependencies are inferred from the claim text.