Nor-seco-bis-nor-seco, tris-nor-seco, and higher nor-seco-cucurbit[n]uril compounds
AssigneeUniversity of Maryland
InventorsLyle David Isaacs, Wei-Hao Huang
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Abstract
Nor-seco-type cucurbit[n]uril compounds and methylene bridged glycoluril oligomers are produced by reacting glycoluril and formaldehyde in strong organic or mineral acid at a temperature adequate to condense the reactants. These compounds are characterized by lacking —CH2— groups rendering their internal cavities more open and, for example, more responsive to guest compounds.
Claims14
A nor-seco cucurbit[n]uril compound or bis-nor-seco cucurbit[n]uril compound, each of which optionally contains a guest compound therein, wherein n has a value of from 5 to 10.
Isolated and purified enantiomers of chiral [CB]n compounds, the chiral CB[n] compounds being selected from the group consisting of chiral nor-seco-CB[n] and chiral bis-nor-seco-CB[n] compounds, wherein n is from 5 to 10.
Dependencies are inferred from the claim text.