High IV melt phase polyester polymer catalyzed with antimony containing compounds
AssigneeGrupo Petrotemex, S.A. de C.V.
InventorsMary Therese Jernigan, Michael Paul Ekart, Richard Gill Bonner
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AssigneeGrupo Petrotemex, S.A. de C.V.
InventorsMary Therese Jernigan, Michael Paul Ekart, Richard Gill Bonner
Estimating the term…
A melt phase process for making a polyester polymer melt phase product by adding an antimony containing catalyst to the melt phase, polycondensing the melt containing said catalyst in the melt phase until the It.V. of the melt reaches at least 0.75 dL/g. Polyester polymer melt phase pellets containing antimony residues and having an It.V. of at least 0.75 dL/g are obtained without solid state polymerization. The polyester polymer pellets containing antimony residues and having an It.V. of at least 0.70 dL/g obtained without increasing the molecular weight of the melt phase product by solid state polymerization are fed to an extruder, melted to produce a molten polyester polymer, and extruded through a die to form shaped articles. The melt phase products and articles made thereby have low b* color and/or high L* brightness, and the reaction time to make the melt phase products is short.
A process for making a polyester polymer comprising polycondensing a melt in the presence of an antimony-containing catalyst to produce a melt phase product, wherein the reaction time of the melt between an It.V. of 0.45 dL/g and an It.V. ranging from 0.70 dL/g to 0.90 dL/g is 100 minutes or less.
A polyester polymer melt phase product having a degree of crystallinity of at least 25% and an It.V. of at least 0.70 dL/g without solid state polymerizing the polymer, said product comprising antimony residues and having a b* color of −5 to +5 and an L* of at least 70.
A melt phase process for making a polyester polymer melt phase product comprising adding an antimony containing catalyst to the melt phase, polycondensing a melt containing said catalyst in the melt phase until the It.V. of the melt reaches at least 0.75 dL/g.
Dependencies are inferred from the claim text.