Curable organopolysiloxane composition and semiconductor device
AssigneeDow Corning Toray Co., Ltd.
InventorsTakashi Sagawa, Masayoshi Terada, Makoto Yoshitake
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Abstract
A curable organopolysiloxane composition comprising: (A) an organopolysiloxane that contains in one molecule at least two alkenyl groups and at least 30 mole % of all silicon-bonded monovalent hydrocarbon groups in the form of aryl groups: (B) an organopolysiloxane that contains in one molecule at least two silicon-bonded hydrogen atoms and at least 15 mole % of all silicon-bonded organic groups in the form of aryl groups; (C) a branched-chain organopolysiloxane that contains alkenyl, aryl, and epoxy-containing organic groups; and (D) a hydrosilylation catalyst. The composition is capable of forming a cured body that has a high index of refraction and strong adhesion to substrates.
Claims15
A curable organopolysiloxane composition comprising:
- (A) an organopolysiloxane of the following average structural formula:
- R1aSiO(4-a)/2
- (wherein R1 designates unsubstituted or halogen-substituted monovalent hydrocarbon groups;
- however, in one molecule at least two groups designated by R1 are alkenyl groups and at least 30 mole % of all groups designated by R1 are aryl groups;
- and “a” is a number ranging from 0.6 to 2.1);
- (B) an organopolysiloxane that contains in one molecule at least two silicon-bonded hydrogen atoms and at least 15 mole % of all silicon-bonded organic groups in the form of aryl groups;
- (C) a branched-chain organopolysiloxane of the following average unit formula:
- (R2SiO3/2)b(R22SiO2/2)c(R23SiO1/2)d(SiO4/2)e(XO1/2)f
- {wherein each R2 independently designates an alkyl group, alkenyl group, aryl group, or an epoxy-containing organic group;
- however, in one molecule at least 5 mole % of all groups designated by R2 are alkenyl groups, at least 15 mole % of all groups designated by R2 are aryl groups, and at least 10 mole % of all groups designated by R2 are epoxy-containing organic groups;
- X designates a hydrogen atom or an alkyl group;
- and “b” is a positive number, “c” is 0 or a positive number,“d” is 0 or a positive number, “e” is 0 or a positive number, “f” is 0 or a positive number, “c/b” is a number ranging from 0 to 10, “d/b” is a number ranging from 0 to 5, “e/(b+c+d+e)” is a number ranging from 0 to 0.3, and
- “f/(b+c+d+e)” is a number ranging from 0 to 0.02};
- and
- (D) a hydrosilylation catalyst;
- wherein component (B) is used in such an amount that the mole ratio of the silicon-bonded hydrogen atoms contained in component (B) to the alkenyl groups contained in components (A) and (C) is in the range of 0.1 to 5;
- component (C) is contained in an amount of 0.1 to 20 parts by mass per 100 parts by mass of the sum of components (A) and (B);
- and
- component (D) is contained in an amount sufficient to accelerate curing of the composition.
Dependencies are inferred from the claim text.