Laundry care compositions with thiazolium dye

A laundry care composition comprising a thiazolium dye suitable for hueing of a fabric and a laundry care ingredient, wherein the thiazolium dye is selected from an azo dye of the general Formula (V);

• wherein:
• a.) R1 is selected from a branched or unbranched (C1-C22)-alkyl moiety, an aromatic alkyl moiety, a polyalkylene oxide moiety or a moiety having Formula (VI) below;
• wherein
• (i) R2 is selected from hydrogen, methyl, ethyl, propyl, acetate or a hydroxyl moiety;
• m and p are, independently, integers from 0 to (n−1), with the proviso that n is an integer from 1 to 6 and m+p=(n−1)
• (ii) Y is selected from a hydroxyl, sulfonate, sulfate, carboxylate or acetate moiety;
• b.) R3 and R4:
• i.) are independently selected from hydrogen;
• a saturated or unsaturated (C1-C22)-alkyl moiety;
• a hydroxy-(C2-C22)-alkyl moiety;
• a hydroxy-(C2-C22)-alkyl moiety comprising, in addition to the hydroxyl oxygen, an oxygen atom;
• a polyether moiety;
• an amino-(C1-C22)-alkyl moiety;
• a substituted or unsubstituted phenyl moiety;
• a substituted or unsubstituted benzyl moiety;
• a (C1-C22)-alkyl moiety terminated in sulfonate, sulfate, acetate, or carboxylate;
• or
• ii.) when taken together form a saturated or unsaturated heterocyclic or carbocyclic moiety;
• or
• iii.) when taken together form a saturated or unsaturated heterocyclic or carbocyclic moiety substituted by, sulfate, sulfonate, phosphate, nitrate, and carboxylate;
• c.) X is moiety having Formula VII below;
• wherein:
• i.) R5 and R6:
• (a) are independently selected from hydrogen;
• a saturated or unsaturated (C1-C22)-alkyl moiety;
• a hydroxy-(C2-C22)-alkyl moiety;
• a hydroxy-(C2-C22)-alkyl moiety comprising, in addition to the hydroxyl oxygen, an oxygen atom;
• a capped or uncapped polyether moiety;
• an amino-(C1-C22)-alkyl moiety;
• a substituted or unsubstituted phenyl moiety;
• a substituted or unsubstituted benzyl moiety;
• a (C1-C22)-alkyl moiety comprising a terminating C1-C4 alkyl ether, sulfonate, sulfate, acetate or carboxylate moiety;
• a thiazole moiety, provided that when R5 and R6 are a capped or uncapped polyether moiety, R5 and R6 each comprise, independently, from 2 to 20 ethylene oxide units, or
• (b) when taken together form a saturated or unsaturated heterocyclic moiety;
• (c) when taken together form a saturated or unsaturated heterocyclic moiety substituted by one or more, alkoxylate, sulfate, sulfonate, phosphate, nitrate, and/or carboxylate moieties;
• (d) when taken together with R7, R8, or R7 and R8 form one or more saturated or unsaturated heterocyclic moieties, optionally substituted by one or more alkoxylate, sulfate, sulfonate, phosphate, nitrate, and/or carboxylate moieties;
• (e) when taken together form a thiazole moiety;
• ii.) R7 and R8 may be independently selected from hydrogen or a saturated or unsaturated alkyl moiety;
• d.) Q− is an anion that balances the overall charge of the compound of Formula I, and the index q is 0 or 1,
• said thiazolium dye providing a hueing efficiency of greater than 10 but less than 40.