High discharge capacity lithium battery
AssigneeEveready Battery Company, Inc.
InventorsJack W Marple, Michael W Wemple
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Abstract
A lithium/iron disulfide electrochemical battery cell with a high discharge capacity. The cell has a lithium negative electrode, an iron disulfide positive electrode and a nonaqueous electrolyte. The iron disulfide of the positive electrode has a controlled average particle size range which allows the electrochemical cells to exhibit desired properties in both low and high rate applications. In various embodiments, the iron disulfide particles are wet milled, preferably utilizing a media mill or milled utilizing a non-mechanical mill such as a jet mill, which reduces the iron disulfide particles to a desired average particle size range for incorporation into the positive electrode.
Claims22
A process for preparing a cathode, comprising the steps of
- selecting a cathode mixture comprising at least 92 wt. % of iron disulfide particles having a mean diameter of a volume distribution of the particles that is greater than or equal to 20 μm,
- non-mechanically milling the active material to reduce the mean diameter of the iron disulfide particles to between 1 and 19 μm,
- forming a slurry comprising the milled active material and coating the slurry to at least a portion of each side of a cathode substrate, and
- drying the cathode.
Dependencies are inferred from the claim text.